N,N,N’,N’-Tetramethyl-O-(N-succinimidyl)uronium Tetrafluoroborate N,N,N’,N’-四甲基-O-(N-琥珀酰亚胺基)脲四氟硼酸盐
CAS 105832-38-0 MFCD00077875
化学结构图
SMILES: CN(C)C(ON1C(=O)CCC1=O)=[N+](C)C.F[B-](F)(F)F
化学属性
| Mol. Formula | C9 |
|---|---|
| Mol. Weight | 301 |
| Melting Point | 198-201 |
| TSCA | No |
| Density | 1.422 |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | N,N,N’,N’-Tetramethyl-O-(N-succinimidyl)uronium Tetrafluoroborate |
|---|---|
| Synonym | N,N,N′,N′-四甲基-O-(N-琥珀酰亚胺)脲四氟硼酸盐 O-(N-Succinimidyl)-N,N,N′,N′-tetramethyluronium tetrafluoroborate O-(N-琥珀酰亚胺基)-N N N'N'-四甲基四氟硼酸脲 O-(N-琥珀酰亚胺基)-N,N,N′,N′-四甲基四氟硼酸脲 O-(N-琥珀酰亚胺基)-N,N,N′,N′-四甲基四氟硼酸脲 TSTU TSTU |
| MDL Number | MFCD00077875 |
| PubChem Substance ID | 24864036 |
| CAS Number | 105832-38-0 |
| Reaxys-RN | 4345014 |
| EC Number | 000-000-0 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | N,N,N’,N’-四甲基-O-(N-琥珀酰亚胺基)脲四氟硼酸盐 |
| LabNetwork Molecule ID | LN00169064 |
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分类
- {SA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
- {SNA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
产品应用
- 用于制备N-琥珀亚胺活泼酯.
相关文献及参考
- FT-IR 2 (1), 1352:D / RegBook 1 (1), 933:H / Structure Index 1 , 145:B:4
- Reagent for the formation of succinimidyl active esters, used for attaching Ru complexes to 5'-amino modified oligonuleotides for use in time-resolved fluorescence techniques: Helv. Chim. Acta, 71, 2085 (1988). In situ formation of succinimidyl active esters can be used in peptide coupling in aqueous solutions: Tetrahedron Lett., 30, 1927 (1989). For peptide reagents, see Appendix 6.
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P301+P330+P331+P310
- P303+P361+P353+P310+P363
- P304+P340
- P305+P351+P338
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H302 Harmful if swallowed 吞食有害
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- 在CH3CN中的溶解度为0.1g/ml，澄清。
