O-(Benzotriazol-1-yl)-N,N,N’,N’-tetramethyluronium Tetrafluoroborate (TBTU) O-苯并三氮唑-N,N,N,N-四甲基脲四氟硼酸酯(TBTU)
CAS 125700-67-6 MFCD00077413
化学结构图
SMILES: CN(C)C(On1nnc2ccccc21)=[N+](C)C.F[B-](F)(F)F
化学属性
| Mol. Formula | C11H16BF4N5O |
|---|---|
| Mol. Weight | 321 |
| Melting Point | 205 |
| TSCA | No |
| Density | 1.422 |
| pH | :A |
别名和识别编码
| Chemical Name | O-(Benzotriazol-1-yl)-N,N,N’,N’-tetramethyluronium Tetrafluoroborate (TBTU) |
|---|---|
| Synonym | N,N,N,N-Tetramethyl-O-(benzotriazol-1-yl)uronium tetrafluoroborate N,N,N′,N′-Tetramethyl-O-(benzotriazol-1-yl)uronium tetrafluoroborate TBTU TBTU 苯并三唑四甲基四氟硼酸 |
| Beilstein Registry Number | 7066325 |
| PubChem Substance ID | 87564559 |
| CAS Number | 125700-67-6 |
| MDL Number | MFCD00077413 |
| Reaxys-RN | 7066325 |
| EC Number | 423-040-4 |
| Chemical Name Translation | O-苯并三氮唑-N,N,N,N-四甲基脲四氟硼酸酯(TBTU) |
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分类
- {SNA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
产品应用
- 偶联试剂，用于固相多肽合成。
相关文献及参考
- 1. I. Abdelmoty et al. Lett. Pept. Sci. 1 , 57, (1994)
- I. Abdelmoty Lett. Pept. Sci. 1 , 57, (1994)
- 2. S. Zimmer et al., C.H. Schneider and A.N. Eberle, eds. Proc. 22nd Eur. Pept. Symp.: Peptides 1992 Leiden 1993, p. 393
- S. Zimmer, C.H. Schneider and A.N. Eberle, eds. Proc. 22nd Eur. Pept. Symp.: Peptides 1992 Leiden , (1993), 393
- Fieser 12 ,44
- FT-NMR 1 (3), 192:C / RegBook 1 (2), 2447:F / Structure Index 1 , 387:A:6
安全信息
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol
- H228 Flammable solid 易燃固体
- H302 Harmful if swallowed 吞食有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
