(Tert-Butoxycarbonylmethyl)Triphenylphosphanium Bromide (叔丁氧基羰基甲基)三苯基溴化磷
CAS 59159-39-6 MFCD00075527
化学结构图
SMILES: [Br-].CC(C)(C)OC(=O)C[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | C24H26BrO2P |
|---|---|
| Mol. Weight | 457 |
| Melting Point | 178 |
| TSCA | No |
别名和识别编码
| Chemical Name | (Tert-Butoxycarbonylmethyl)Triphenylphosphanium Bromide |
|---|---|
| Synonym | Carbo-tert-butoxymethyl triphenylphosphonium bromide NSC 82468 (叔丁氧基羰基甲基)溴化三苯基磷 |
| MDL Number | MFCD00075527 |
| PubChem Substance ID | 135727355 |
| CAS Number | 59159-39-6 |
| Beilstein Registry Number | 4631405 |
| Chemical Name Translation | (叔丁氧基羰基甲基)三苯基溴化磷 |
| LabNetwork Molecule ID | LN00223787 |
| Reaxys-RN | 4631405 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
相关文献及参考
- 1. Huang, Y.; et al. Adv. Synth. Catal. 351 , 1423, (2009)
- 2. Prasada Raju, V. V. N. K. V.; et al. Org. Process Res. Dev. 13 , 710, (2009)
- 3. Nishimoto, Y.; et al. J. Org. Chem. 73 , 9465, (2008)
- 4. Cabral dos Santos, L.; et al. Heterocycles 73 , 751, (2007)
- 5. Suzuki, Y.; Sato, M. Tetrahedron Lett. 45 , 1679, (2004)
- 6. Railton, C. J.; Clive, Derrick L. J. Carbohydr. Res. 281 , 69, (1996)
- FT-NMR 1 (2), 1678:B / RegBook 1 (2), 2279:E / Structure Index 1 , 357:B:1
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
