(R)-N,N-Dimethyl-1-[(S)-1',2-Bis(Diphenylphosphino)Ferrocenyl]Ethylamine (R)-N,N-二甲基-1-[(S)-1',2-双(二苯基膦基)二茂铁基]乙胺

CAS 74311-56-1 MFCD00075284

化学结构图

74311-56-1
SMILES: [Fe].C[C@H]([C]1[CH][CH][CH][C]1P(C1C=CC=CC=1)C1C=CC=CC=1)N(C)C.C1=CC=CC=C1P(C1C=CC=CC=1)[C]1[CH][CH][CH][CH]1 |^1:3,4,5,6,7,37,38,39,40,41|

化学属性

Mol. FormulaC38H37FeNP2
Mol. Weight625.51
Melting Point138.0 to 144.0 deg-C

别名和识别编码

Chemical Name(R)-N,N-Dimethyl-1-[(S)-1',2-Bis(Diphenylphosphino)Ferrocenyl]Ethylamine
Synonym [R,R]-1-[1-二甲基氨乙基]-1′,2-双[二苯基膦]二茂铁 (-)-(R)-N,N-二甲基-1-[(S)-1′,2-双(二苯基膦基)二茂铁基]乙胺
MDL NumberMFCD00075284
PubChem Substance ID87568960
CAS Number74311-56-1
Chemical Name Translation(R)-N,N-二甲基-1-[(S)-1',2-双(二苯基膦基)二茂铁基]乙胺
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+P340+P312
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P332+P313
  • P302+P352+P312+P362+P364
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P305+P351+P338+P337+P313
Hazard statements
  • H302+H312+H332
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Other Chiral Ligands - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Other Chiral Ligands - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metallocenes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物

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