(Bicyclo[2.2.1]Hepta-2,5-Diene)[1,4-Bis(Diphenylphosphino)Butane]Rhodium(I) Tetrafluoroborate (二环[2.2.1]庚-2,5-二烯)[1,4-二(二苯基膦基)丁烷]四氟硼酸铑(I)

CAS 82499-43-2 MFCD00075218

化学结构图

82499-43-2
SMILES: [Rh+].F[B-](F)(F)F.C1C2C=CC1C=C2.C(CCCP(C1C=CC=CC=1)C1C=CC=CC=1)P(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC35H36BF4P2Rh
Mol. Weight708.32
Melting Point210 °C (dec.)(lit.)

别名和识别编码

Chemical Name(Bicyclo[2.2.1]Hepta-2,5-Diene)[1,4-Bis(Diphenylphosphino)Butane]Rhodium(I) Tetrafluoroborate
MDL NumberMFCD00075218
PubChem Substance ID24860905
Synonym (二环[2.2.1]庚-2,5-二烯)[1,4-二(二苯基膦基)丁烷]四氟硼酸铑(I)
Chemical Name Translation(二环[2.2.1]庚-2,5-二烯)[1,4-二(二苯基膦基)丁烷]四氟硼酸铑(I)
CAS Number82499-43-2
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium Catalysts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

系列性分类


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