2-(1,3-Dioxolan-2-Yl)Ethyltriphenylphosphonium Bromide 2-(1,3-二氧戊环-2-基)乙基三苯基溴化鏻

CAS 86608-70-0 MFCD00075119

化学结构图

86608-70-0
SMILES: [Br-].C(C[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)C1OCCO1

化学属性

Mol. FormulaC23H24BrO2P
Mol. Weight443
Melting Point144-146 °C(lit.)

别名和识别编码

Chemical Name2-(1,3-Dioxolan-2-Yl)Ethyltriphenylphosphonium Bromide
MDL NumberMFCD00075119
PubChem Substance ID87568506
Beilstein Registry Number5209374
CAS Number86608-70-0
EC Number404-940-6
Reaxys-RN5209374
Synonym 2-(1,3-二氧戊环-2-基)乙基三苯基溴化鏻
Chemical Name Translation2-(1,3-二氧戊环-2-基)乙基三苯基溴化鏻
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 1. Kaiser, A.; et al. J. Org. Chem. 64 , 3778, (1999)
  • 2. Wijtmans, M.; et al. J. Med. Chem. 54 , 1693, (2011)
  • 3. Cashman, J. R.; et al. J. Med. Chem. 52 , 1530, (2009)
  • FT-IR 2 (2), 3334:B / FT-NMR 1 (2), 1674:A / RegBook 1 (2), 2277:B / Structure Index 1 , 356:A:5

安全信息

WGK Germany2
GHS Symbol
Precautionary statements
  • P305+P351+P338
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H318 Causes serious eye damage 严重伤害眼睛
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word {} {} {TCI} Danger
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
  • S22 Do not breathe dust 不要吸入粉尘；
Risk Statements
  • R33 Danger of cumulative effects 有累积作用的危险
  • R52/53
  • R22 Harmful if swallowed 吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Others - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Wittig & Horner-Emmons Reaction
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Dioxanes & Dioxolanes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Phosphonium Compounds

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