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• 试剂商城
• 直接询价

分类

• {SA} Chemical Synthesis, Materials Science, Micro/NanoElectronics, Others, Oxidizing Agents, Ruthenium, Solution Deposition Precursors, Synthetic Reagents
• {SNA} Chemical Synthesis, Micro/NanoElectronics, Other Oxidizing Agents, Oxidizing Agents, Ruthenium, Solution Deposition Precursors, Synthetic Reagents, 材料科学
• {SNA} Chemical Synthesis, Others, Oxidizing Agents, Synthetic Reagents
• Chemical Synthesis, Materials Science, Micro/NanoElectronics, Others, Oxidation, Ruthenium, Solution Deposition Prec

产品应用

• 可溶、非挥发性、空气稳定的温和催化剂，可与适当的共?氧化剂按化学计量或作为催化用途使用。
• 氧化剂，用于将 N,N′-二羟基咪唑啉转化为氮氧自由基。将羟基取代的三-正丁基铵三氟硼酸盐氧化成醛和酮，而?不会伴随碳-硼键的断裂。

相关文献及参考

• 3. Synthesis 7 , 639-666, (1994)
• Selective, catalytic oxidant introduced by Ley. Normally used in combination with N-methylmorpholine-N-oxide as the stoichiometric reoxidant and 4A molecular sieves to remove water. Preferred solvents are dichloromethane and acetonitrile. Primary and secondary alcohols are oxidized to aldehydes and ketones in high yield: J. Chem. Soc., Chem. Commun., 1625 (1987). For an example of alcohol to aldehyde oxidation in the partial synthesis of the acyl tetronic acid ionophore tetronasin, see: Tetrahedron Lett., 35, 319 (1994). Also useful for a number of other oxidations such as lactols to lactones and sulfides to sulfones. For oxidation of secondary amines to imines, and of hydroxylamines to nitrones, see: Tetrahedron Lett., 35, 6567, 6571 (1994).
• Merck: 14,10463
• For a comprehensive review of this reagent, see: Synthesis, 639 (1994). For a review of ruthenium oxo-complexes as organic oxidants, see: Chem. Soc. Rev., 21, 179 (1992).
• For a brief feature on uses in synthesis, see: Synlett, 824 (2007).

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