(-)-Diisopinocampheyl Chloroborane (-)-二异松蒎基氯硼烷

CAS 85116-37-6 MFCD00074807

化学结构图

85116-37-6
SMILES: C[C@H]1[C@H](B(Cl)[C@@H]2C[C@@H]3C[C@H]([C@H]2C)C3(C)C)C[C@@H]2C[C@H]1C2(C)C

化学属性

Mol. FormulaC20H34BCl
Mol. Weight321
Density0.88
Melting Point52-56 °C(lit.)
Flash Point82 °F
Boiling Point66-69°C
Refractive index-51 ° (C=neat)

别名和识别编码

Chemical Name(-)-Diisopinocampheyl Chloroborane
Synonym {uni_hamburg} (-)-DIP-CHLORIDE (-)-IPC2BCL (-)-BETA-CHLORODIISOPINOCAMPHEYLBORANE (-)-β-Chlordiisopinocampheylboran (-)-B-DIISOPINOCAMPHEYL-CHLOROBORANE (-)-DIP-CHLORIDE(TM) (-)-B-CHLORODIISOPINOCAMPHEYLBORANE Borane, chlorobis[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]- (-)-二异松蒎基氯硼烷 (-)-B-Chlorodiisopinocampheylborane (-)-B-CHLORODIISOPINOCAMPHENYLBORANE (-)二异松蒎基氯硼烷 (-)-DIP-Chloride™ 氯化二异松香芹硼烷 Diisopinocampheylchloroborane (+)-二异松蒎基氯硼烷 (-)-DIP-CHLORIDE, 50-65 WT% IN HEPTANE (-)-Diisopinocampheyl chloroborane (-)-DIP-CHLORIDE, 60-75 WT% IN HEXANES (-)-SS-CHLORODIISOPINOCAMPHEYLBORANE (-)-dip-chloride tm solution C20H34BCl (-)-B-chlorodiisopinocampheylborane (-)-b-chlorodiisopinocampherylborane (-)-Diisopinocampheylchloroborane, in heptanes, 2M solution (-)-DIP-Chloride (-)-diisopinocampheylchloroborane,(-)-dpc,inheptanes (-)-Diisopinocampheylchloroborane, in hexanes, 2M solution (-)-DIP CHLORIDE, 65-75 WT% IN ALPHA-PI& (-)-DIP-Cl (-)-Dip-chloride (-)-DIP-Chloride™ 溶液 (-)-Chlorodiisopinocampheylborane (-)-diisopinocampheylchloroborane,(-)-dpc,inhexanes (-)-B-二异松蒎基氯硼烷 (-)-Ipc2BCl (-)-Diisopinocampheylboron chloride Borane, chlorobis(2,6,6-trimethylbicyclo[3.1.1]hept-3-yl)-, [1R-[1α,2β,3α(1R*,2S*,3R*,5R*),5α]]-
MDL NumberMFCD00074807
PubChem Substance ID87566610
Beilstein Registry Number5937756
CAS Number85116-37-6
EC Number250-023-7
Reaxys-RN5937756
Chemical Name Translation(-)-二异松蒎基氯硼烷
InChIInChI=1S/C20H34BCl/c1-11-15-7-13(19(15,3)4)9-17(11)21(22)18-10-14-8-16(12(18)2)20(14,5)6/h11-18H,7-10H2,1-6H3/t11-,12-,13+,14+,15-,16-,17-,18-/m1/s1
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分类

  • {uni_hamburg} no charge; carbocycle; alicycle; fused rings; 4ring; 6ring; chiral; 1fragment
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Reduction

相关文献及参考

  • Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.

安全信息

WGK Germany3
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P313
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Signal word
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R50/53
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R34 Causes burns 会导致灼伤
  • R10 Flammable 易燃
  • R37 Irritating to respiratory system 刺激呼吸道
Packing GroupII
Storage condition 0-10 0-10°C 2-8°C 密封2-8°C保存
UN Number 2924 UN 3261 8/PG 2
Hazard Class3/8

其他信息

  • MOL 文件:85116-37-6.mol
  • F:10-21
  • Sigma Aldrich:85116-37-6(sigmaaldrich)
  • (-)-二异松蒎基氯硼烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1615 (-)-B-二异松蒎基氯硼烷(60%的己烷溶液,约1.7mol/L) (-)-B-Chlorodiisopinocampheylborane (60% in Hexane, ca. 1.7mol/L) 100ML 2570元 2014/06/02 C2023 (-)-B-二异松蒎基氯硼烷(60%的庚烷溶液,约1.7mol/L) (-)-B-Chlorodiisopinocampheylborane (60% in Heptane, ca. 1.7mol/L) 100ML 989元
  • 和水反应
  • TCI Shanghai:(-)-二异松蒎基氯硼烷(60%的正己烷溶液,约1.7mol/L) (-)-B-Chlorodiisopinocampheylborane (60% in Hexane, ca. 1.7mol/L)(85116-37-6)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Reduction - Chiral Catalysts, Ligands, and Reagents

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