Boron trifluoride methanol complex solution 三氟化硼甲醇络合物
CAS 2802-68-8 MFCD00071635
化学结构图
SMILES:
化学属性
| Mol. Formula | C H4 O . B F3 |
|---|---|
| Mol. Weight | 99.848 |
| Density | 0.859 g/mL at 25 °C |
| Flash Point | 29°C(lit.) |
| TSCA | Yes |
| Boiling Point | 59 |
| Refractive index | 1.34 |
| Autoignition Point | 788 °F |
| Vapor Pressure | 19.5 mmHg ( 20 °C) |
| Melting Point | -20 |
| Stability | 对湿度敏感 |
| Solubility | 水解 |
别名和识别编码
| Chemical Name | Boron trifluoride methanol complex solution |
|---|---|
| CAS Number | 2802-68-8 |
| Reaxys-RN | 3611499 |
| Merck Number | 1349 |
| MDL Number | MFCD00071635 |
| PubChem Substance ID | 87563865 |
| Beilstein Registry Number | 3693581 |
| EC Number | 220-543-9 |
| Synonym | Boron Trifluoride - Methanol Complex {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { |
| Chemical Name Translation | 三氟化硼甲醇络合物 |
| InChIKey | WWNADQBMJRRNDS-UHFFFAOYSA-L |
| Chemicalbook ID | CB6501776 |
| LabNetwork Molecule ID | LN00162977 |
| InChI | InChI=1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3; |
| Canonical SMILES | FB(F)F.CO |
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分类
- {SNA} Acids, Acids & Bases, Boron, Boron Catalysts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Lewis Acids, Synthetic Reagents
- {SNA} Boron,
- {SNA} Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents GC, Reagents for Acylation, Reagents for Alkylation & Esterification
- {SNA} 25mL Sure/Seal Reagents, Boron, Catalysis and Inorganic Chemistry, Chemical Synthesis, Lewis Acids, Organometallic Reagents, Synthetic Reagents
- {SNA} Boron, Catalysis and Inorganic Chemistry, Chemical Synthesis, Electronic Chemicals, Fluor
相关文献及参考
- Beil. 1 ,IV,1220
- Fieser 1 ,73 / Fieser 9 ,64
- Aldrich MSDS 1 , 220:C / Corp MSDS 1 (1), 484:A / Corp MSDS 1 (1), 484:B / Sigma FT-IR 1 (2), 1017:B / Structure Index 1 , 479:A:8
- Reagent for esterification of acids: J. Chem. Soc., 5770 (1965); and also for the selective cleavage of trityl ethers: Carbohydr. Res., 65, 132 (1978).
安全信息
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H370 Causes damage to organs 导致器官损伤
- H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H301+H311+H331
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H332 Harmful if inhaled 吸入有害
- H302 Harmful if swallowed 吞食有害
- H302+H332
- H331 Toxic if inhaled 吸入中毒
- H311 Toxic in contact with skin 皮肤接触中毒
- H301 Toxic if swallowed 吞食有毒
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P301+P310
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P403+P233
- P305+P351+P338+P310
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P301+P330+P331+P310
- P303+P361+P353
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P370+P378
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P304+P340+P310
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P233 Keep container tightly closed. ?保持容器密闭。
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P308+P311
- P241+P242+P243
- P303+P361+P353+P310+P363
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- R11 Highly flammable 非常易燃
- R26 Very toxic by inhalation 吸入极毒
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
- R48/23
- R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
- R35 Causes severe burns 会导致严重灼伤
- R34 Causes burns 会导致灼伤
- R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
- R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
- R14 Reacts violently with water 遇水会猛烈反应
其他信息
- PackingGroup:II
- HazardClass:8
- EPA化学物质信息:Borate(1-), trifluoromethoxy-, (T-4)-, hydrogen, compd. with methanol (1:1)(2802-68-8)
- 敏感性:Moisture Sensitive
- 三氟化硼甲醇络合物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0894 三氟化硼-甲醇络合物 Boron Trifluoride - Methanol Complex 500ML 837元 2014/06/02 B0894 三氟化硼-甲醇络合物 Boron Trifluoride - Methanol Complex 100ML 292元 2010/06/21 158900500 三氟化硼甲醇络合物 Boron trifluoride dimethanol complex , 50-52 wt% BF3 50 GR 399元
