(2-Aminobenzyl)Triphenylphosphonium Bromide (2-氨基苯甲基)三苯基溴化磷
CAS 78133-84-3 MFCD00066987
化学结构图
SMILES: [Br-].NC1C=CC=CC=1C[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | H2NC6H4CH2P(C6H5)3Br |
|---|---|
| Mol. Weight | 448.33 |
| Melting Point | 245 °C (dec.)(lit.) |
别名和识别编码
| Chemical Name | (2-Aminobenzyl)Triphenylphosphonium Bromide |
|---|---|
| MDL Number | MFCD00066987 |
| PubChem Substance ID | 24869256 |
| CAS Number | 78133-84-3 |
| Synonym | (2-氨基苯甲基)三苯基溴化膦 |
| Chemical Name Translation | (2-氨基苯甲基)三苯基溴化磷 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
相关文献及参考
- 3. Tao, M.; et al. Bioorg. Med. Chem. Lett. 16 , 938, (2006)
- 1. Kraus, G. A.; Guo, H. Tetrahedron Lett. 51 , 4137, (2010)
- 2. Kraus, G. A.; Guo, H. J. Org. Chem. 74 , 5337, (2009)
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
