(1S,2S)-Cyclohexane-1,2-Diol (1S,2S)-反式-1,2-环己二醇

CAS 57794-08-8 MFCD00066431

化学结构图

57794-08-8
SMILES: O[C@@H]1CCCC[C@H]1O |&1:1,6|

化学属性

Mol. FormulaC6H10(OH)2
Mol. Weight116.16
Melting Point107-109 °C(lit.)

别名和识别编码

Chemical Name(1S,2S)-Cyclohexane-1,2-Diol
Synonym (1S,2S)-反式-1,2-环己二醇 (1S)-反-1,2-环己二醇
CAS Number57794-08-8
PubChem Substance ID24866402
Beilstein Registry Number1901343
MDL NumberMFCD00066431
Chemical Name Translation(1S,2S)-反式-1,2-环己二醇
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Polyols
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Polyols

相关文献及参考

  • 1. Marshall, J.A. Xie, S. J. Org. Chem. 60 , 7230, (1995)
  • 2. Stolle, A. et al. Tetrahedron Lett. 35 , 3521, (1994)
  • 3. Burk, M.J. et al. J. Am. Chem. Soc. 115 , 10125, (1993)
  • 4. Burk, M.J. et al. Tetrahedron Asymmetry 2 , 569, (1991)
  • 5. Pichon, M. Figadere, B. Tetrahedron Asymmetry 7 , 927, (1996)
  • 6. Matteson, D.S. Man, H.-W. J. Org. Chem. 59 , 5734, (1994)
  • 7. Ho, O.C. et al. Organometallics 14 , 2855, (1995)
  • Beil. 6 ,IV,5193
  • Fieser 17 ,91
  • FT-IR 2 (1), 228:B / Structure Index 1 , 21:B:1

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
Risk Statements
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险

系列性分类


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