(R)-2-Phenyloxirane (R)-环氧苯乙烷

CAS 20780-53-4 MFCD00066210

化学结构图

20780-53-4
SMILES: C1CCC([C@@H]2CO2)CC1

化学属性

Mol. FormulaC8H8O
Mol. Weight120
Refractive index1.5340 to 1.5380
Boiling Point194°C(lit.)
Density1.051 g/mL at 25 °C(lit.)
Flash Point77°C
TSCANo
Autoignition Point928 °F
Melting Point-37 ºC
Solubility不溶

别名和识别编码

Chemical Name(R)-2-Phenyloxirane
Synonym (R)-(+)-环氧乙基苯 (R)-环氧苯乙烷 (R)-(Epoxyethyl)benzene (R)-(+)-Epoxystyrene (R)-(+)-环氧乙基苯 (R)-Phenyloxirane (R)-环氧苯乙烷 R-Phenyloxirane (R)-(+)-氧化苯乙烯 (R)-(+)-Epoxystyrene(R)-(+)-2-Phenyloxirane
Beilstein Registry Number17(5)1,577
CAS Number20780-53-4
PubChem Substance ID253662332
MDL NumberMFCD00066210
InChIKeyAWMVMTVKBNGEAK-QMMMGPOBSA-N
Chemical Name Translation(R)-环氧苯乙烷
Reaxys-RN1984
Wiswesser Line NotationT3OTJ BR
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks

相关文献及参考

  • 1. O. De Lucchi et al. Tetrahedron Lett. 28 , 107, (1987)
  • 2. S. Calet et al. J. Am. Chem. Soc. 111 , 931, (1989)
  • 3. M. Movassaghi, E.N. Jacobsen J. Am. Chem. Soc. 124 , 2456, (2002) 摘要
  • Beil. 17 ,V,1,577

安全信息

GHS Symbol
WGK Germany3
Hazard Codes T
Hazard statements
  • H350 May cause cancer 可能致癌
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H312 Harmful in contact with skin 皮肤接触有害
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSCZ9625010
Precautionary statements
  • P305+P351+P338
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P308+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P403+P233
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P370+P378
Signal word Danger
UN Number UN2810 2810
Risk Statements
  • R45 May cause cancer 可能致癌
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R36 Irritating to eyes 刺激眼睛
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
Packing GroupIII
Hazard Class6.1 
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 2 umol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 298,197,1993

TYPE OF TEST            : Mutation test systems - not otherwise specified
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 298,197,1993

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 125 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 278,289,1992

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Epoxides - Organic Building Blocks

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