CAS 133-90-4 MFCD00065093-Chloramben 3-amino-2,5-dichlorobenzoic acid TAO{mole}

Chloramben 3-amino-2,5-dichlorobenzoic acid

CAS 133-90-4 MFCD00065093

化学结构图

SMILES: Nc1cc(Cl)cc(C(=O)O)c1Cl

化学属性

Mol. Formula	C₇H₅Cl₂NO₂
Mol. Weight	206.03
Melting Point	196 - 200°C
Solubility	700 MG/L (25 ºC)
Density	1.607
Boiling Point

别名和识别编码

Chemical Name	Chloramben
Beilstein Registry Number	2365906
PubChem Substance ID	24849246
CAS Number	133-90-4
EC Number	205-123-5
MDL Number	MFCD00065093
Synonym	2,5-Dichloro-3-aminobenzoic acid 2,5-dichloro-3-aminobenzoic acid 2,5-dichloro-3-aminobenzoicacid 3-AMINO-2,5-DICHLOROBENZOIC ACID 3-Amino-2,5-dichlorbenzoesäure 3-Amino-2,5-dichlorobenzoic Acid {Chemicalbook} CHLORAMBEN Chlora Chlorambed {} {Chemicalbook} Benzoic acid, 3-amino-2,5-dichloro- {} {} {uni_hamburg} Amoben {} {} {} {uni_hamburg} Amibin {} {} {} {} {Chemblink} Amiben; 3-Amino-2,5-dichlorobenzoic acid {} {} {} {} {} {Chemicalbook} Amiben,Vegiben {} {} {} {} {} {} {Chemicalbook} Amiben ds {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {hazard_com} Amiben DS {} {} {} {} {} {} {} {} {uni_hamburg} Amiben {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} Ambiben {} {} {} {} {} {} {} {} {} {} {Chemicalbook} Acpm-629 {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} AMIBEN(R) {} {}
Chemical Name Translation	3-amino-2,5-dichlorobenzoic acid
Merck Number	13,2082
Wiswesser Line Notation	ZR BG EG CVQ

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产品应用

用作大豆田的选择芽前除草，也可用于小麦、玉米、西红柿及蔬菜田中的除草。作用对象主要是稗草、马唐、看麦娘、狗尾草等一年生杂草。药害少，不受天气的影响。

安全信息

Precautionary statements

P305+P351+P338
P308+P313
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P201 Obtain special instructions before use. 使用前获取专门指示。

RTECSDG1925000

GHS Symbol

Signal word Danger

Hazard statements

H350 May cause cancer 可能致癌
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Hazard Codes T T;Xn T,Xn

WGK Germany3

Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Eyeshields, Gloves, type P2 (EN 143) respirator cartridges

Safety Statements

S22 Do not breathe dust 不要吸入粉尘；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R45 May cause cancer 可能致癌
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用

UN Number UN 3077 9/PG 3 2588/3077

Storage condition 0-6°C 4

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1344 gm/kg/80W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-25,1977

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 672 gm/kg/80W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-25,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >2200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PEMNDP Pesticide Manual.  (The British Crop Protection Council, 20 Bridport
   Rd., Thornton Heath CR4 7QG, UK)  V.1-    1968-  Volume(issue)/page/year:
   9,136,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 3136 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   WRPCA2 World Review of Pest Control.  (London, UK)  V.1-10, 1962-71.
   Discontinued.  Volume(issue)/page/year: 9,119,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   RREVAH Residue Reviews.  (Springer-Verlag New York, Inc., Service Center, 44
   Hartz Way, Secaucus, NJ 07094)  V.1-    1962-  Volume(issue)/page/year:
   10,97,1965

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3725 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 45(4),74,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 mg/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5(Suppl
   1),3,1983

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 58500 ug/kg
REFERENCE :
   CARYAB Caryologia.  (Via G. LaPira 4, 50121 Florence, Italy)  V.1-    1948-
   Volume(issue)/page/year: 33,527,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   NTPTB* NTP Technical Bulletin.  (National Toxicology Program, Landow Bldg.
   3A-06, 7910 Woodmont Ave., Bethesda, MD 20205)  Volume(issue)/page/year:
   JAN1982

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 234 mg/kg
REFERENCE :
   CARYAB Caryologia.  (Via G. LaPira 4, 50121 Florence, Italy)  V.1-    1948-
   Volume(issue)/page/year: 33,527,1980

其他信息

储运特性:库房通风低温干燥; 与食品原料分开储运
类别:农药
溶于水、丙酮、乙醇、异丙醇。
毒性分级:中毒
MOL 文件:133-90-4.mol
灭火剂:干粉、泡沫、砂土
用途一:用作大豆田的选择芽前除草，也可用于小麦、玉米、西红柿及蔬菜田中的除草。作用对象主要是稗草、马唐、看麦娘、狗尾草等一年生杂草。药害少，不受天气的影响。
方法一:由对二氯苯经多聚甲醛氯甲基化、高锰酸钾氧化、硝酸硝化、锡粒还原而得。
可燃性危险特性:燃烧产生有毒氮氧化物和氯化物气体
TCI Shanghai:3-氨基-2,5-二氯苯甲酸 3-Amino-2,5-dichlorobenzoic Acid,>;98.0%(T)(133-90-4)
Sigma Aldrich:133-90-4(sigmaaldrich)
上游原料:多聚甲醛 --> 对二氯苯 --> 锡粒
急性毒性:口服- 大鼠 LD50: 3500 毫克/ 公斤; 口服- 小鼠 LD50: 3725 毫克/ 公斤
图谱信息:草灭畏(133-90-4)质谱(MS) 草灭畏(133-90-4)红外图谱(IR1) 草灭畏(133-90-4)红外图谱(IR2)
MSDS 信息:3-氨基-2,5-二氯苯甲酸(133-90-4).msds
外观性质:白色无臭结晶。