CAS 70987-78-9 MFCD00064489-(2S)-(+)-Glycidyl tosylate (2S)-(+)-缩水甘油基对甲苯磺酸酯 TAO{mole}

(2S)-(+)-Glycidyl tosylate (2S)-(+)-缩水甘油基对甲苯磺酸酯

CAS 70987-78-9 MFCD00064489

化学结构图

SMILES: CC1=CC=C(C=C1)S(=O)(=O)OC[C@@H]1CO1

化学属性

Mol. Formula	C10H12O4S
Mol. Weight	228
Melting Point	46-49
Flash Point	113°(235°F)
TSCA	No
Density	1.31

别名和识别编码

Chemical Name	(2S)-(+)-Glycidyl tosylate
CAS Number	70987-78-9
Synonym	(2S)-(+)-Glycidyl tosylate (2S)-(+)-缩水甘油对甲苯磺酸酯 (S)-(+)-Glycidyl p-toluenesulfonate, (S)-(+)-Oxirane-2-methanol p-toluenesulfonate (S)-(+)-对甲苯磺酸缩水甘油酯 (S)-(+)-对甲苯磺酸缩水甘油酯 (S)-(+)-环氧乙烷-2-甲醇对甲苯磺酸酯
PubChem Substance ID	24878443
EC Number	417-210-7
Beilstein Registry Number	3592143
MDL Number	MFCD00064489
Reaxys-RN	3592143
Chemical Name Translation	(2S)-(+)-缩水甘油基对甲苯磺酸酯

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产品应用

Protected Glycidol, used as an intermediate in the preparation of neurochemicals.

安全信息

GHS Symbol

WGK Germany3

Hazard Codes 9 T,N

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H350 May cause cancer 可能致癌
H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H318 Causes serious eye damage 严重伤害眼睛
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

RTECSRR0510050

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P350
P302+P352+P333+P313+P362+P364
P305+P351+P338
P305+P351+P338+P310
P308+P313
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

UN Number 3077 UN3077

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
R45 May cause cancer 可能致癌
R51/53
R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险

Packing GroupIII

Hazard Class9

TYPE OF TEST            : Mutation test systems - not otherwise specified
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 298,197,1993

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 nmol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 298,197,1993

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 298,197,1993

TYPE OF TEST            : Sister chromatid exchange
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 298,197,1993