(S)-(+)-Methoxyphenylacetic acid (S)-(+)-Α-甲氧基苯基乙酸

CAS 26164-26-1 MFCD00064216

化学结构图

26164-26-1
SMILES: CO[C@H](C(O)=O)C1C=CC=CC=1

化学属性

Mol. FormulaC9H10O3
Mol. Weight166
Melting Point64-66
TSCANo
Boiling Point130°C/0.7mmHg(lit.)
Density1.422

别名和识别编码

Chemical Name(S)-(+)-Methoxyphenylacetic acid
CAS Number26164-26-1
Synonym (S)-(+)-O-Methylmandelic Acid (S)-(+)-α-甲氧基苯乙酸 (S)-2-Methoxy-2-(phenyl)ethanoic Acid ?-Methoxy-benzeneacetic Acid L-?-Methoxyphenylacetic Acid O-Methyl-L-mandelic acid O-甲基-L-扁桃酸
MDL NumberMFCD00064216
Beilstein Registry Number2361718
EC Number247-492-5
PubChem Substance ID87572827
Reaxys-RN2209197
Chemical Name Translation(S)-(+)-Α-甲氧基苯基乙酸
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分类

  • Chiral Reagents
  • {SNA} Asymmetric Synthesis, Carboxylic Acids, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Organic Building Blocks
  • {SNA} Chiral, Chiral Derivatization Reagents, Chiral LC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC, 分析/色谱, 分析试剂
  • {SNA} Analytical Reagents, Analytical/Chromatography, Chiral, Chiral Derivatization Reagents, Chiral LC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC

相关文献及参考

  • With chiral amines, forms diastereomeric amides which have been used to establish absolute configuration by 1 H NMR: J. Org. Chem., 59, 4202 (1994); 60, 1538 (1995).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Codes Xi

系列性分类


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