(S)-(+)-1-(1-Naphthyl)Ethylisocyanate (s)-(+)-1-(1-萘基)乙基异氰酸酯

CAS 73671-79-1 MFCD00064181

化学结构图

73671-79-1
SMILES: C[C@H](N=C=O)C1C=CC=C2C=CC=CC2=1

化学属性

Mol. FormulaC13H11NO
Mol. Weight197
Refractive index1.6010 to 1.6070
Boiling Point106-108 °C/0.16 mmHg(lit.)
Density1.128 g/mL at 25 °C(lit.)
Flash Point93°C(lit.)
TSCANo

别名和识别编码

Chemical Name(S)-(+)-1-(1-Naphthyl)Ethylisocyanate
Synonym (S)-(+)-1-(1-萘基)乙基异氰酸酯 (S)-NEI
CAS Number73671-79-1
PubChem Substance ID87571751
Beilstein Registry Number4675071
MDL NumberMFCD00064181
Reaxys-RN3607445
Chemical Name Translation(s)-(+)-1-(1-萘基)乙基异氰酸酯
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Asymmetric Synthesis, Chemical Synthesis, Chiral, Chiral Building Blocks, Derivatization Reagents, Derivatization Reagents HPLC, Isocyanates, Organic Building Blocks
  • Analytical Reagents, Analytical/Chromatography, Asymmetric Synthesis,

相关文献及参考

  • Corp MSDS 1 (2), 2515:D / FT-NMR 1 (2), 1573:A / RegBook 1 (2), 2171:C / Structure Index 1 , 341:D:7

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xn
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P342+P311
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P302+P350
  • P337+P313
  • P403+P233
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P305+P351+P338
  • P304+P340+P311
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下，戴呼吸防护。
  • P302+P352+P332+P313+P362+P364
  • P301+P310+P330
  • P305+P351+P338+P337+P313
Signal word Danger {} {} {} {} {TCI}
UN Number 2206 UN2206
Storage condition Moisture Sensitive 0-10 0-10°C
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R42/43
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R42 May cause sensitisation by inhalation 吸入会产生过敏反应
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
Packing GroupIII
Hazard Class6.1

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Chiral Derivatization Reagents - Derivatization Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Isocyanates - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Isocyanates - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Optical Resolution
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块

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