(+)-10-Camphorsulfonic acid (+)-10-樟脑磺酸

CAS 3144-16-9 MFCD00064157

化学结构图

3144-16-9
SMILES: CC1(C)C2CCC1(CS(=O)(=O)O)C(=O)C2

化学属性

Mol. FormulaC10H16O4S
Mol. Weight232.30
Melting Point196-200°C
TSCAYes
Density1.331
Stability易吸潮
Appearance D(+)-10-樟脑磺酸(3144-16-9)为白色结晶体或结晶性粉末，不溶于醚，微溶于冰醋酸、乙酸乙酯，在潮湿的空气中易潮解。熔点195-200℃
SolubilitySOLUBLE
Refractive index21.5 ° (C=5, H2O)
Boiling Point344.46 °C at 760 mmHg

别名和识别编码

Chemical Name(+)-10-Camphorsulfonic acid
Synonym (+)-D-Camphor-10-sulfonic acid {LY} (+)-D-Camphor-10-sulfonic acid {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-D-Camphor-10-sulfonic acid {} {} {} {} {} {}
CAS Number3144-16-9
PubChem Substance ID65617
EC Number221-554-1
Beilstein Registry Number2809675
MDL NumberMFCD00064157
Merck Number1734
Chemical Name Translation(+)-10-樟脑磺酸
Reaxys-RN2809675
LabNetwork Molecule IDLN00190061
InChIInChI=1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1
Canonical SMILESCC1(C)[C@@H]2CC[C@]1(CS(=O)(O)=O)C(C2)=O
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分类

  • {SNA} Analytical Reagents,
  • {SNA} Ana
  • {SA} Analytical Reagents, Analytical/Chromatography, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Derivatization Reagents, Derivatization Reagents HPLC, Organic Building Blocks, Sulfonic/Sulfinic Acids, UV-VIS
  • Analytical Reagents, Analytical/Chromatography, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Derivatization Reagents, Derivatization Reagents HPLC, Organic Building Blocks, Sulfonic/Sulfinic Acids, UV-VIS

产品应用

  • 可作为拆分剂，以及二肽偶联的催化剂。

相关文献及参考

  • Merck: 14,1734
  • Resolving agent for optically-active bases. For an improved resolution technique, using two immiscible solvents and half equivalent of resolving agent, see: Tetrahedron, 41, 2465 (1985). The procedure is claimed to lead to faster resolutions with higher optical purities than conventional methods.
  • Merck: 14,1734 Beilstein:11,314

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 8
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSED1550000
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing GroupII
UN Number 3261
Risk Statements
  • R34 Causes burns 会导致灼伤
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class8 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2502 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PHARAT Pharmazie.  (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18,
   Berlin DDR-1020, Ger. Dem. Rep.)  V.1-    1946-  Volume(issue)/page/year:
   1,150,1946

其他信息

  • 海关编码:29147090
  • 比旋光度:22 ° (589nm, c=20, H2O 25 °C)
  • MSDS 信息:1S-(+)-Camphor-10-sulfonic acid(3144-16-9).msds
  • 用途一:用于医药中间体或异构体产品拆分
  • F:3-10
  • D(+)-10-樟脑磺酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30035224 D-樟脑-10-磺酸 25g 94元 2011/04/16 C0015 (+)-10-樟脑磺酸 (+)-10-Camphorsulfonic Acid 500G 1550元 2011/04/16 C0015 (+)-10-樟脑磺酸 (+)-10-Camphorsulfonic Acid 25G 268元
  • Acros Organics:D(+)-10-樟脑磺酸 D(+)-10-Camphorsulfonic acid, 99%(3144-16-9)
  • 用途二:用于制药工业
  • 图谱信息:D(+)-10-樟脑磺酸(3144-16-9)质谱(MS) D(+)-10-樟脑磺酸(3144-16-9)红外图谱(IR2) D(+)-10-樟脑磺酸(3144-16-9)红外图谱(IR1)
  • Sigma Aldrich:3144-16-9(sigmaaldrich)
  • Alfa Aesar:<2%(3144-16-9)" href="http://www.alfa.com/zh/GP100w.pgm?DSSTK=A16179&CAS;=3144-16-9">(1S)-(+)-樟脑－10－磺酸,98+% (1S)-(+)-Camphor-10-sulfonic acid, 98+%(dry wt.), water <2%(3144-16-9)
  • 检测方法:T
  • 敏感性:Hygroscopic
  • 下游产品:(S)-(+)-3-喹宁醇 --> 盐酸左旋咪唑 --> 7-(3,5,6-三甲基-1,4-苯醌-2-基)-7-苯基庚酸
  • 不溶于醚，微溶于冰醋酸、乙酸乙酯，在潮湿的空气中易潮解。
  • MOL 文件:3144-16-9.mol
  • TCI Shanghai:(+)-10-樟脑磺酸 (+)-10-Camphorsulfonic Acid,>;98.0%(T)(3144-16-9)
  • 用途三:有机合成中间体，拆分剂。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents HPLC - Derivatization Reagents
  5. UV-VIS - Derivatization Reagents HPLC
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Protected Alcohols - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Sulfonic/Sulfinic Acids - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Sulfonic/Sulfinic Acid Salts - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Optical Resolution
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Derivatization Reagents
  4. HPLC Derivatization Reagents, by Application
  5. Thiols
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents HPLC
  4. HPLC Derivatization Reagents, by Application
  5. Thiols
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Terpenes

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