CAS 464-49-3 MFCD00064149-D-Camphor D-樟脑 TAO{mole}

D-Camphor D-樟脑

CAS 464-49-3 MFCD00064149

化学结构图

SMILES: CC1(C)[C@@H]2CC[C@@]1(C)C(=O)C2

化学属性

Mol. Formula	C10H16O
Mol. Weight	152
Melting Point	179-181
Density	5.24
Flash Point	65°(149°F)
TSCA	Yes
Boiling Point	204°C(lit.)
Autoignition Point	870 °F
Vapor Density	5.24 (vs air)
Vapor Pressure	4 mmHg ( 70 °C)
Refractive index	44.5 ° (C=20, EtOH)
Solubility	Soluble in ethanol (5%),

别名和识别编码

Chemical Name	D-Camphor
MDL Number	MFCD00064149
CAS Number	464-49-3
Synonym	(+)-2-Bornanone (+)-Camphor (+)-樟脑 (1R)-1,7,7-三甲基二环[2.2.1]庚烷-2-酮 (1R)-(+)-樟脑 (1R)-1,7,7-三甲基二环[2.2.1]庚烷-2-酮 2-莰酮,天然樟脑 7,7-trimethyl-(1r)-bicyclo(2.2.1)heptan-2-on Alcanfor Bicyclo(2.2.1)heptan-2-one, 1,7,7-trimethyl-, (1R)- CAMPHOR Camphor USP Camphor, (+)- D(+)-CAMPHOR D(+)-樟脑（天然） D(-)-CAMPHOR D-(+)-Camphor D-2-Bornanone D-2-CAMPHANONE D-2-KETO-1,7,7-TRIMETHYLNORCAMPHANE D-Camphor FEMA 2230 Japanese camphor bicyclo[2.2.1]heptan-2-one,1,7,7-trimethyl-,(1R)- camphora d-2-Bornanone Α-莰酮右旋樟脑(天然樟脑) 樟腦
PubChem Substance ID	159055
EC Number	207-355-2
Beilstein Registry Number	2042745
Merck Number	1732
Chemical Name Translation	D-樟脑
Reaxys-RN	1907611
Wiswesser Line Notation	L55 A CVTJ A1 A1 B1
LabNetwork Molecule ID	LN00241548
InChI	InChI=1S/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3/t7-,10+/m1/s1

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分类

{SNA} Analytical Standard
{SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Ketones, Organic Building Blocks
{SNA} A-F,
{SNA} A-F, All Alphabetically Sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Basil, C, CA - CG, Camphor, Chromatography, Cinnamon, Flavors and Fragrances, Food & Beverage Standards, Food Products & Beverages, Fragrance Allergens in Cosmetic Products, Herbs & Spices, Laurel, Lavender, Rosemary, Substance Classification, Terpene

产品应用

手性中间体和助剂

安全信息

GHS Symbol

WGK Germany1

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H228 Flammable solid 易燃固体
H302 Harmful if swallowed 吞食有害
H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
H312 Harmful in contact with skin 皮肤接触有害
H315 Causes skin irritation 会刺激皮肤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H319 Causes serious eye irritation 严重刺激眼睛
H330 Fatal if inhaled 吸入致命
H332 Harmful if inhaled 吸入有害
H335 May cause respiratory irritation 可能导致呼吸道刺激
H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
H371 May cause damage to organs 可能导致器官损伤
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。

Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

RTECSEX1260000

Precautionary statements

P203
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P301+P310
P301+P312
P301+P312+P330
P301+P316
P301+P317
P302+P352
P303+P361+P353
P304+P312
P304+P340
P305+P351+P338
P305+P351+P338+P337+P313
P308+P316
P309+P311
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P316
P317
P318
P319
P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P331 Do NOT induce vomiting.. 不要催吐。
P332+P313
P332+P317
P333+P313
P333+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P403+P233
P403+P235

Signal word Warning

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；

Packing GroupIII

UN Number 2717 UN 2717 4.1/PG 3 UN2717

Risk Statements

R11 Highly flammable 非常易燃
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Hazard Codes 4.1 F,Xn

Hazard Class4.1

TYPE OF TEST            : LD90 - Lethal Dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 525 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 16,665,1978

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 16,665,1978

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 16,665,1978

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2200 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 16,665,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1310 mg/kg
TOXIC EFFECTS :
   Details o

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 4 gm/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Maternal Effects - other effects
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB92-170034

其他信息

食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称允许使用该种添加剂的食品中文名称添加剂功能最大允许使用量（g/kg）最大允许残留量（g/kg） d-樟脑食品食品用香料用于配制香精的各香料成分不得超过在GB 2760中的最大允许使用量和最大允许残留量
Sigma Aldrich:464-49-3(sigmaaldrich)
D-樟脑价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 C0010 (+)-樟脑 (+)-Camphor 500G 649元 2014/06/02 C0010 (+)-樟脑 (+)-Camphor 25G 117元 2010/06/21 227841000 D-樟脑 D(+)-Camphor 97% 100 GR 374元
蒸气压:4 mm Hg ( 70 °C)
类别:易燃固体
可燃性危险特性:遇明火, 高温, 氧化剂可燃烧; 受热分解辛辣刺激烟雾
溶解度: 1 G/800ML 水(25°C) 1g溶于1 ML 乙醇, 1 ML 乙醚, 0.5 ML 氯仿, 0.4 ML 苯, 0.4 ML 丙酮, 1.5 ML 松节油, 0.5 ML 冰醋酸. 溶于苯胺、硝基苯、二硫化碳、四氢萘、十氢萘和石油醚。
毒性分级:中毒
爆炸物危险特性:蒸汽遇明火, 高温, 氧化剂可爆炸
Acros Organics:D(+)-樟脑 D(+)-Camphor, 97%(464-49-3)
储运特性:库房低温通风干燥; 与氧化剂分开存放; 防明火, 高温
下游产品:(R)-(+)-降冰片胺 --> 三3-(三氟甲基羟基亚甲基)-D-樟脑铕 --> 3-三氟乙酰基-D-樟脑 --> 降龙涎香醚
蒸气密度:5.24 (vs air)
灭火剂:水雾, 二氧化碳, 干粉, 泡沫
TCI Shanghai:(+)-樟脑 (+)-Camphor,>;98.0%(GC)(464-49-3)
急性毒性:腹腔-大鼠 LD50: 3500 毫克/公斤; 口服-小鼠 LD50: 1310 毫克/公斤
FEMA:2230
刺激数据:皮肤-兔 500 毫克/24小时轻度
Alfa Aesar:(1R)-(+)-樟脑,98% (1R)-(+)-Camphor, 98%(464-49-3)
图谱信息:D-樟脑(464-49-3)红外图谱(IR1) D-樟脑(464-49-3)红外图谱(IR2) D-樟脑(464-49-3)核磁图( 13 CNMR) D-樟脑(464-49-3)质谱(MS)
MOL 文件:464-49-3.mol