Methyl (R)-(-)-3-hydroxybutyrate, 99% (R)-3-羟基丁酸甲酯

CAS 3976-69-0 MFCD00063289

化学结构图

3976-69-0
SMILES: COC(=O)C[C@@H](C)O

化学属性

Mol. FormulaC5H10O3
Mol. Weight118.13
Refractive index1.4200 to 1.4230
Boiling Point161.9°C at 760 mmHg
Density1.055
Flash Point73°C
TSCANo
Solubility易溶于水。

别名和识别编码

Chemical NameMethyl (R)-(-)-3-hydroxybutyrate, 99%
CAS Number3976-69-0
Alfabeta NameMETHYLHYDROXYBUTANOATE R3()--
MDL NumberMFCD00063289
PubChem Substance ID2724279
EC Number223-610-0
Beilstein Registry Number3648161
Reaxys-RN3648161
Synonym (R)-Methyl 3-hydroxybutanoate {LY} (R)-Methyl 3-hydroxybutanoate {} {LY} (R)-Methyl 3-hydroxybutanoate {} {} {LY} (R)-Methyl 3-hydroxybutanoate {} {} {} {LY} (R)-Methyl 3-hydroxybutanoate {} {} {} {} {LY} (R)-Methyl 3-hydroxybutanoate {} {} {} {} {} {LY} (R)-Methyl 3-hydroxybutanoate {} {} {} {} {} {} {LY} (R)-Methyl 3-hydroxybutanoate {} {} {} {} {} {} {} {LY} (R)-Methyl 3-hydroxybutanoate {} {} {} {} {} {} {} {} {LY} (R)-Methyl 3-hydroxybutanoate {} {} {} {} {} {} {} {} {} {LY} (R)-Methyl 3-hydroxybutanoate {} {} {} {} {} {} {} {} {} {} {LY} (R)-Methyl 3-hydroxybutanoate {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-Methyl 3-hydroxybutanoate {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-Methyl 3-hydroxybutanoate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-Methyl 3-hydroxybutanoate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-Methyl 3-hydroxy
Chemical Name Translation(R)-3-羟基丁酸甲酯
LabNetwork Molecule IDLN00007127
InChIInChI=1S/C5H10O3/c1-4(6)3-5(7)8-2/h4,6H,3H2,1-2H3/t4-/m1/s1
Canonical SMILESC[C@@H](O)CC(OC)=O
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Esters, Organic Building Blocks
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Esters, Organic Building Blocks

产品应用

  • 具有光学活性的原料

相关文献及参考

  • For use in the synthesis of chiral ß-lactams, see: J. Chem. Soc., Chem. Commun., 1376 (1988).
  • For use in the synthesis of chiral ß-lactams, see: J. Chem. Soc., Chem. Commun., 1376 (1988).
  • Can undergo aldol-type reactions with aldehydes with either syn- or anti-selectivity according to the conditions: Chem. Lett., 1931 (1990).
  • Can undergo aldol-type reactions with aldehydes with either syn- or anti-selectivity according to the conditions: Chem. Lett., 1931 (1990).

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • Acros Organics:(R)-3-羟基丁酸甲酯 Methyl (R)-(-)-3-hydroxybutyrate, 99%(3976-69-0)
  • 比旋光度:-21.5 ° (neat)
  • MOL 文件:3976-69-0.mol
  • MSDS 信息:3-羟基丁酸甲酯(3976-69-0).msds
  • Sigma Aldrich:3976-69-0(sigmaaldrich)
  • Alfa Aesar:(R)-(-)-3-羟丁酸甲酯,98% Methyl (R)-(-)-3-hydroxybutyrate, 98%(3976-69-0)
  • (R)-3-羟基丁酸甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0705 (R)-(-)-3-羟基丁酸甲酯 Methyl (R)-(-)-3-Hydroxybutyrate 10ML 1410元 2014/06/02 H0705 (R)-(-)-3-羟基丁酸甲酯 Methyl (R)-(-)-3-Hydroxybutyrate 25ML 2810元 2010/06/21 SB01506FA (R)-3-羟基丁酸甲酯 Methyl 3-(R)-hydroxybutyrate 100 GR 9000元
  • 外观性质:无色、有水果香味的液体。
  • TCI Shanghai:(R)-(-)-3-羟基正丁酸甲酯 Methyl (R)-(-)-3-Hydroxybutyrate,>;98.0%(GC)(3976-69-0)

系列性分类


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