(+)-Methyl (R)-2-Chloropropionate (+)-(R)-2-氯丙酸甲酯

CAS 77287-29-7 MFCD00062940

化学结构图

77287-29-7
SMILES: COC(=O)[C@@H](C)Cl

化学属性

Mol. FormulaC4H7ClO2
Mol. Weight122.55
Refractive index1.4160 to 1.4200
Boiling Point134°C(lit.)
Density1.152
Flash Point37°C(lit.)

别名和识别编码

Chemical Name(+)-Methyl (R)-2-Chloropropionate
Synonym (+)-(R)-2-氯丙酸甲酯 (R)-(+)-2-氯丙酸甲酯
CAS Number77287-29-7
PubChem Substance ID87566626
EC Number278-658-5
Beilstein Registry Number2,248
MDL NumberMFCD00062940
Chemical Name Translation(+)-(R)-2-氯丙酸甲酯
Reaxys-RN1720590
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Esters, Organic Building Blocks
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Esters, Organic Building Blocks

相关文献及参考

  • Aldrich MSDS 1 , 1227:D / Corp MSDS 1 (2), 2319:B / FT-NMR 1 (1), 1014:A / RegBook 1 (1), 737:G / Sigma FT-IR 1 (1), 1379:B / Structure Index 1 , 113:D:5 / Vapor Phase 3 , 705:B
  • Beil. 2 ,H,248

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P302+P352+P332+P313+P362+P364
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P305+P351+P338+P337+P313
  • P303+P361+P353
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Class3
UN Number 2933
Packing GroupIII
Warnings 危化品目录(2015) 危险化学品

系列性分类


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