1,3-Dibromo-5-fluorobenzene 1,3-二溴-5-氟苯

CAS 1435-51-4 MFCD00061119

化学结构图

1435-51-4
SMILES: Fc1cc(Br)cc(Br)c1

化学属性

Mol. FormulaC6H3Br2F
Mol. Weight253.90
Boiling Point213.9°C at 760 mmHg
Density2.018
Refractive index1.5760 to 1.5800
Flash Point101.7°C
TSCANo
Appearance 淡黄色液体。沸点204℃-206℃(768mmHg),闪点>101℃,折光率1.5770,比重2.018。

别名和识别编码

Chemical Name1,3-Dibromo-5-fluorobenzene
CAS Number1435-51-4
Alfabeta NameDIBROMOFLUOROBENZENE 135---,
MDL NumberMFCD00061119
EC Number250-023-7
Beilstein Registry Number2353462
PubChem Substance ID137003
Synonym 1,3-Dibromo-5-fluorobenzene {LY} 1,3-Dibromo-5-fluorobenzene {} {LY} 1,3-Dibromo-5-fluorobenzene {} {} {LY} 1,3-Dibromo-5-fluorobenzene {} {} {} {LY} 1,3-Dibromo-5-fluorobenzene {} {} {} {} {LY} 1,3-Dibromo-5-fluorobenzene {} {} {} {} {} {LY} 1,3-Dibromo-5-fluorobenzene {} {} {} {} {} {} {LY} 1,3-Dibromo-5-fluorobenzene {} {} {} {} {} {} {} {LY} 1,3-Dibromo-5-fluorobenzene {} {} {} {} {} {} {} {} {LY} 1,3-Dibromo-5-fluorobenzene {} {} {} {} {} {} {} {} {} {LY} 1,3-Dibromo-5-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Dibromo-5-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Dibromo-5-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Dibromo-5-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Dibromo-5-fluorobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Dibromo-5-fluorobenzene {} {} {} {} {} {} {} {} {} {} {}
Reaxys-RN2353462
Chemical Name Translation1,3-二溴-5-氟苯
InChIKeyASWYHZXKFSLNLN-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008409
Canonical SMILESFC1=CC(Br)=CC(Br)=C1
InChIInChI=1S/C6H3Br2F/c7-4-1-5(8)3-6(9)2-4/h1-3H
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分类

  • {SNA} Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis, Fluorinated Building Blocks, Halogenated Hydrocarbons, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks

相关文献及参考

  • Lithiation with lithium 2,2,6,6-tetramethylpiperidide at -75o occurs at the 4-position, affording 2,4-dibromo-6-fluorobenzoic acid in 81% yield after carboxylation: Tetrahedron Lett., 37, 6551 (1996).

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Personal Protective Equipment Eyeshields, Gloves
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • TCI Shanghai:1,3-二溴-5-氟苯 1,3-Dibromo-5-fluorobenzene,>;98.0%(GC)(1435-51-4)
  • 用途一:医药、农药、液晶材料中间体。
  • Alfa Aesar:1,3-二溴-5-氟苯,98+% 1,3-Dibromo-5-fluorobenzene, 98+%(1435-51-4)
  • Acros Organics:1,3-Dibromo-5-fluorobenzene, 98%(1435-51-4)
  • Hazard Note:Irritant
  • 1,3-二溴-5-氟苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2211 1,3-二溴-5-氟苯 1,3-Dibromo-5-fluorobenzene 25G 1140元 2014/06/02 D2211 1,3-二溴-5-氟苯 1,3-Dibromo-5-fluorobenzene 10G 588元 2010/06/21 263460250 1,3-二溴-5-氟苯 1,3-Dibromo-5-fluorobenzene 98% 25 GR 1225元
  • Sigma Aldrich:1435-51-4(sigmaaldrich)
  • 1,3-二溴-5-氟苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D2211 1,3-二溴-5-氟苯 1,3-Dibromo-5-fluorobenzene 25G 1400元 2011/04/16 D2211 1,3-二溴-5-氟苯 1,3-Dibromo-5-fluorobenzene 10G 767元 2010/06/21 263460250 1,3-二溴-5-氟苯 1,3-Dibromo-5-fluorobenzene 98% 25 GR 1225元
  • 图谱信息:1,3-二溴-5-氟苯(1435-51-4)核磁图( 1 HNMR) 1,3-二溴-5-氟苯(1435-51-4)红外图谱(IR1) 1,3-二溴-5-氟苯(1435-51-4)质谱(MS) 1,3-二溴-5-氟苯(1435-51-4)核磁图( 13 CNMR)
  • MOL 文件:1435-51-4.mol
  • 检测方法:GC,NMR

系列性分类


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