Bis(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Barium(Ii) Hydrate 双(2,2,6,6,-四甲基-3,5-庚二酮)钡(Ii)水合物

CAS 17594-47-7 MFCD00058709

化学结构图

17594-47-7
SMILES: CC(C)(C)/C(=C/C(=O)C(C)(C)C)/O[Ba]O/C(=C\C(=O)C(C)(C)C)/C(C)(C)C

化学属性

Mol. FormulaBa(OCC(CH3)3CHCOC(CH3)3)2· xH2O
Mol. Weight503.86 (anhydrous basis)
Melting Point175-180 °C(lit.)
TSCANo
Boiling Point225°/0.3mm
Appearance white pwdr.
Stabilitymoisture sensitive

别名和识别编码

Chemical NameBis(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Barium(Ii) Hydrate
Synonym Barium bis(2,2,6,6-tetramethyl-3,5-heptanedionate) Bis(2,2,6,6-tetramethyl-3,5 heptanedionato)barium (II) Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)barium (II) Ba(TMHD)2 Barium dipivaloylmethanate Barium bis(dipivaloylmethane) Barium bis(dipivaloylmethanate) Barium, bis(2,2,6,6-tetramethyl-3,5-heptanedionato)- Bis(2,2,6,6-tetramethyl-3,5-heptanedionato-κO,κO')barium Barium bis(2,2,6-6-tetramethyl-3,5-heptanedione) Bis(dipivaloylmethanato)barium 双(2,2,6,6-四甲基-3,5-庚二酮酸)钡 水合物 Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)barium Bis(dipivaloylmethanato)barium(II) Barium-thd Barium bis(2,2,6,6-tetramethylheptanedioate) Barium-DPM hydrate Dipivaloylmethane barium salt 3,5-Heptanedione, 2,2,6,6-tetramethyl-, ion(1-), barium Barium-dpm 双(2,2,6,6,-四甲基-3,5-庚二酮酸)钡(一水)
MDL NumberMFCD06200255
CAS Number17594-47-7
Chemical Name Translation双(2,2,6,6,-四甲基-3,5-庚二酮)钡(Ii)水合物
PubChem Substance ID24862341
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分类

  • {SNA} Barium, CVD and ALD Precursors by Metal, Micro/NanoElectronics, Vapor Deposition Precursors, 材料科学

相关文献及参考

  • Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.

安全信息

Safety Statements
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Packing GroupIII
UN Number UN1564
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
Storage condition Hygroscopic
Hazard Codes T
WGK Germany1
GHS Symbol
Precautionary statements
  • P301+P310
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛

系列性分类


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