(4S)-4-(2-Chlorophenyl)-2-Hydroxy-5,5-Dimethyl-1,3,2-Dioxaphosphinane 2-Oxide (S)-(-)-4-(2-氯苯基)-5,5-二甲基-2-羟基-1,3,2-二氧磷杂环己烷-2-氧化物
CAS 98674-86-3 MFCD00055615
化学结构图
SMILES: CC1(C)COP(=O)(O)O[C@@H]1c1ccccc1Cl
化学属性
| Mol. Formula | C11H14ClO4P |
|---|---|
| Mol. Weight | 277 |
| Melting Point | 228-234 °C(lit.) |
别名和识别编码
| Chemical Name | (4S)-4-(2-Chlorophenyl)-2-Hydroxy-5,5-Dimethyl-1,3,2-Dioxaphosphinane 2-Oxide |
|---|---|
| CAS Number | 98674-86-3 |
| Alfabeta Name | CHLOCYPHOS S(())--- |
| MDL Number | MFCD00055615 |
| PubChem Substance ID | 24870176 |
| Chemical Name Translation | (S)-(-)-4-(2-氯苯基)-5,5-二甲基-2-羟基-1,3,2-二氧磷杂环己烷-2-氧化物 |
| Synonym | (S)-(-)-4-(2-氯苯基)-2-羟基-5,5-二甲基-1,3,2-二氧磷杂环己烷 2-氧化物 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Organic Phosphates/Phosphites
- {KO} Misc
- {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Organic Phosphates/Phosphites
相关文献及参考
- 1. ten Hoeve, W. and Wynberg, H. J. Org. Chem. 50 , 4508, (1985)
- 2. ten Hoeve, W., and Wynberg, H. Synth. Commun. 24 , 899, (1994)
- 3. Van der Haest, A.D. et al. Rec. Trav. Chim. 109 , 523, (1990)
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
