4-Amino-6-(Tert-Butyl)-3-(Methylthio)-1,2,4-Triazin-5(4H)-One 4-氨基-6-(叔丁基)-3-(甲硫基)-1,2,4-三嗪-5(4H)-酮

CAS 21087-64-9 MFCD00055525

化学结构图

21087-64-9
SMILES: CSC1=NN=C(C(=O)N1N)C(C)(C)C

化学属性

Mol. FormulaC8H14N4OS
Mol. Weight214.32
Melting Point125 ºC
Density1.28
Solubility略溶于水

别名和识别编码

Chemical Name4-Amino-6-(Tert-Butyl)-3-(Methylthio)-1,2,4-Triazin-5(4H)-One
CAS Number21087-64-9
Synonym Sencor DF 4-Amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)-one 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5-one Lexone 4L metribuzin (ISO) 4-Amino-6-(1,1-dimethylethyl)-3-methylthio-1,2,4-triazin-5(4H)-on Bayer 6159H 4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5-(4H)-one ######## Lexone DF Bayer 6443H Metribuzin 1,2,4-Triazin-5(4H)-one, 4-amino-6-(1,1-dimethylethyl)-3-(methylthio)- Sencorex DIC 1468 BAY 94337 NTN 70 4-Amino-6-tert.-butyl-3-methylthio-1,2,4-triazin-5-on 4-Amino-6-tert-butyl-3-(methylthio)-1,2,4-triazin-5-one metribuzin 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one Lexone 4-Amino-6-tert-butyl-3-(methylthio)-1,2,4-triazin-5(4H)-one; 4-Amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)-one; Bay 94337; Bayer 6159H; Lexone 4L; Lexone 75DF; Preview; Salute; Sencor 4L; Sencor 75DF; Sencoral Bayer 94337 4-Amino-6-tert-butyl-3-methylthio-as-triazin-5-one Sencor 4 4-Amino-6-tert-butyl-3-methylthio-1'2'4-triazin-5(4H)-on Zenkor 嗪草酮 BAY dic 1468 4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-4(5H)-one Sencoral Sencor Sencorer BAY 61597 1,2,4-Triazin-5-one, 4-amino-6-tert-butyl-3-(methylthio)-
Beilstein Registry Number0746650
MDL NumberMFCD00055525
EC Number244-209-7
Wiswesser Line NotationT6NN DNVJ CS1 DZ FX1&1&1
Chemical Name Translation4-氨基-6-(叔丁基)-3-(甲硫基)-1,2,4-三嗪-5(4H)-酮
LabNetwork Molecule IDLN00465365
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分类

  • Agro-Products
  • Amines
  • Aromatics
  • Heterocycles
  • Inhibitors
  • Pharmaceuticals
  • Intermediates & Fine Chemicals
  • {uni_hamburg} no charge; nitrogen heterocycle; 6RingOnly; 6ring; amide; lactame; 1fragment
  • {SNA} Alphabetical Index of Analytical Standards, Method and Regulation Specific, All alphabetically sorted, Analytical Standards, Analytical/Chromatography, Chromatography, EPA, Endocrine Disruptors (Draft), Environmental Standards, H-M, Herbicides, M, METI - MZ, Pesticides & Metabolites, Triazinone structure

产品应用

  • Metribuzin is an is an aminotriazinone herbicide used in agriculture for both pre- and post-emergence in crops including soy bean, potatoes, tomatoes and sugar cane. Metribuzin acts by inhibiting phot

相关文献及参考

  • Undabeytia, T.S. et al.: Pest. Man. Sci., 67, 271 (2011); Souza M. et al.: Wee Sci., 26, 318 (1978); Renger, G.: Zeitsch. Naturfrosch. C J. Biosci., 34C, 1010 (1979);
  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H312 Harmful in contact with skin 皮肤接触有害
  • H302 Harmful if swallowed 吞食有害
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
WGK Germany3
Signal word Danger Warning
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RTECSXZ2990000
Hazard Codes Xn;N Xn,N
Safety Statements
  • S2 Keep out of the reach of children 避免儿童触及；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R50/53 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 239 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NNGADV Nippon Noyaku Gakkaishi.  Journal of the Pesticide Science Society of
   Japan.  (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170,
   Japan)  V.1-    1976-  Volume(issue

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >860 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NNGADV Nippon Noyaku Gakkaishi.  Journal of the Pesticide Science Society of
   Japan.  (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170,
   Japan)  V.1-    1976-  Volume(issue)/page/year: 12,127,1987

TYPE OF TEST            : LC - Lethal concentr

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd,
   eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year:
   A280,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : 168 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FMCHA2 Farm Chemicals Handbook.  (Meister Pub., 37841 Euclid Ave.,
   Willoughy, OH 44094)  Volume(issue)/page/year: -,C204,1991

TYPE OF TEST

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1 gm/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - extra-embryonic structures
   (e.g., placenta, umbilical cord)
REFERENCE :
   NNGADV Nippon Noyaku Gakkaishi.  Journal of the Pesticide Science Society of
   Japan.  (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170,
   Japan)  V.1-    1976-  Volume(issue)/page/year: 12,127,1987

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Method Specific - Analytical Standards
  4. EPA - Method Specific
  5. Endocrine Disruptors (Draft) - EPA
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. M - Alphabetic
  5. METI - MZ - M

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