CAS 6164-98-3 MFCD00055257-Chlordimeform 正己烷中杀虫脒溶液 TAO{mole}

Chlordimeform 正己烷中杀虫脒溶液

CAS 6164-98-3 MFCD00055257

化学结构图

SMILES: Cc1cc(Cl)ccc1N=CN(C)C

化学属性

Mol. Formula	C10H13ClN2
Mol. Weight	196.70
Solubility	微溶于水、苯、氯仿。
Density	1.1
Refractive index	1.558
Boiling Point	163-165°C
Melting Point	32°C

别名和识别编码

Chemical Name	Chlordimeform
Synonym	1-(2-Methyl-4-chlorophenyl)-3,3-dimethylformamidine Acaron C 8514 CHLORDIMEFORM CHLORPHENAMIDINE(R) Chlordimeform Chlordimeform emulsion(content>10%) Chlorfenamidine Chlorphenamidine Formamidine, N,N-dimethyl-N'-(2-methyl-4-chlorophenyl)- Fundal GLAECRON(R) Gal Galecron Methanimidamide, N'-(4-chlor N'-(2-Methyl-4-chlorophenyl)-N,N-dimethylformamidine N'-(4- N'-(4-chloro-2-methylphenyl)-N,N-dimethyl methanimidamide N'-(4-chloro-2-methylphenyl)-N,N-dimethylmethanimidamide N'2-(4-chloro-o-tolyl)-N'1,N'1-dimethylformamidine N' N'-(4-CHLORO-O-TOLYL)-N,N-DIMETHYL FORMAMIDINE N(sup 2)-(4-Chloro-o-tolyl)-N(sup 1),N(sup 1)-d
MDL Number	MFCD00055257
CAS Number	6164-98-3
Beilstein Registry Number	2088124
EC Number	228-200-5
Chemical Name Translation	正己烷中杀虫脒溶液
Merck Number	13,2100
Wiswesser Line Notation	GR C1 DNU1N1&1
PubChem Substance ID	22544
InChI	InChI=1S/C10H13ClN2/c1-8-6-9(11)4-5-10(8)12-7-13(2)3/h4-7H,1-3H3

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产品应用

有机氮杀虫剂。有良好的内吸作用，有较好的杀虫，杀螨效果。主要用于防治水稻螟虫，也可用于防治棉花红蜘蛛，红铃虫和果树红蜘蛛，介壳虫等。一般稀释为300-500倍喷雾。每亩田月用杀虫脒原药50g。杀虫脒代谢产物的毒性问题曾有争议，使用时应严格按照农业部门的规定。该品对蚕高毒，在蚕桑地区使用时应特别注意。不宜与碱性农药混用。

安全信息

RTECSLQ4375000

GHS Symbol

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P203
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P301+P312
P301+P316
P301+P317
P302+P352
P304+P340
P305+P351+P338
P308+P313
P308+P316
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P316
P317
P318
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P317
P337+P317
P361+P364
P362+P364
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H302 Harmful if swallowed 吞食有害
H302+H312
H312 Harmful in contact with skin 皮肤接触有害
H351 Suspected of causing cancer 怀疑致癌
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。

WGK Germany1

Signal word Warning

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Safety Statements

S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S22 Do not breathe dust 不要吸入粉尘；

Hazard Codes Xn,N

Risk Statements

R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R50/53

Storage condition 储存温度2-8°C 2-8°C

UN Number 2761

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 6552 mg/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Vascular - tumors
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   CHYCDW Zhonghua Yufangyixue Zazhi.  Chinese Journal of Preventive Medicine.
   (China International Book Trading Corp., POB 2820, Beijing, Peop. Rep.
   China)  Beginning history not known.  Volume(issue)/page/year: 19,154,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 625 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College
   Science Pub., 1969  Volume(issue)/page/year: 5,43,1976

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : >5800 mg/m3/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd,
   eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year:
   A074,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 263 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   7,299,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Roden

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 225 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SPEADM Special Publication of the Entomological Society of America.  (4603
   Calvert Rd., College Park, MD 20740)  Volume(issue)/page/year: 78-1,21,1978

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 5 ppm
REFERENCE :
   RSTUDV Rivista di Scienza e Technologia degli Alimenti e di Nutrizione
   Umana.  Review of Science and Technology of Food and Human Nutrition.
   (Bologna, Italy)  V.5-6, 1975-76.  Discontinued.  Volume(issue)/page/year:
   6,161,1976

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Human HeLa cell
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   BECTA6 Bulletin of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   07094)  V.1-    1966-  Volume(issue)/page/year: 11,184,1974

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Human HeLa cell
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   BECTA6 Bulletin of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   07094)  V.1-    1966-  Volume(issue)/page/year: 11,184,1974

TYPE OF TEST            : Specific locus test
ROUTE OF EXPOSURE       : Multiple routes
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 10 ppb
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   25,148,1995

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 2 umol/plate
REFERENCE :
   JAFCAU Journal of Agricultural and Food Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC
   20037)  V.1-    1953-  Volume(issue)/page/year: 34,157,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1800 ug/kg
SEX/DURATION            : female 5-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - behavioral
REFERENCE :
   BECTA6 Bulletin of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   07094)  V.1-    1966-  Volume(issue)/page/year: 20,760,1978

其他信息

杀虫脒价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80149480 杀虫脒;N-(2-甲基-4-氯苯基)-N′,N′-二; N′-(4-氯甲苯基)-N,N-二甲基甲; 氯苯脒; 杀螨螟; 杀螨脒; 克死螨; 杀螟螨 g 1250元
MOL 文件:6164-98-3.mol
生产方法:杀虫脒有多种合成路线：（1）光气法；以100%杀虫脒计原料消耗定额：光气790kg/t、二甲基甲酰氯480kg/t、邻甲苯胺640kg/t、氯气410kg/t。（2）氧氯化磷法；（3）氯化亚砜法；（4）对甲苯磺酰氯法等等。
RTECS号:LQ4375000
外观性质:白色结晶，有氨的气味。
用途:有机氮杀虫剂。有良好的内吸作用，有较好的杀虫、杀螨效果。主要用于防治水稻螟虫，也可用于防治棉花红蜘蛛、红铃虫和果树红蜘蛛、介壳虫等。一般稀释为300-500倍喷雾。每亩田约用杀虫脒原药50g。杀虫脒代谢产物的毒性问题曾有争议，使用时应严格按照农业部门的规定。该品对蚕高毒，在蚕桑地区使用时应特别注意。不宜与碱性农药混用。
PackingGroup:III
HazardClass:6.1(b)
20℃的蒸气压为0.047pa.20℃时在水中溶解度为250ppm，易溶于有机溶剂。商品为其盐酸盐水溶液。纯品杀虫脒盐酸盐，易溶于水，难溶于有机溶剂，在酸性溶液中稳定，中性溶液中易析出结晶，遇碱分解。