Naled 二溴磷

CAS 300-76-5 MFCD00053227

化学结构图

300-76-5
SMILES: COP(=O)(OC)OC(Br)C(Cl)(Cl)Br

化学属性

Mol. FormulaC4H7Br2Cl2O4P
Mol. Weight380.80
Solubility不溶于水,易溶于芳烃,不溶于脂肪。
Density2.032
Boiling Point110°C
Melting Point26°C

别名和识别编码

Chemical NameNaled
CAS Number300-76-5
Synonym O,O-Dimethyl-O-(1,2-dibrom-2,2-dichlor-aethyl)-phosphat 二溴灵 O-(1,2-Dibromo-2,2-dicloro-etil)-O,O-dimetil-fosfato Bromex (insecticide) Dibrom dimethyl-1,2-dibromo-2,2-dichloroethylphosphate 二溴磷乳油(50%) 二溴磷标准品 1,2-dibromo-2,2-dichloro-ethanodimethylphosphate DIBROM (NALED) BRP arthodibrom RE-4355 {Ch O,O-Dimethyl O-2,2-dichloro-1,2-dibromoethyl phosphate 1,2-二溴-2,2-二氯 O-(1,2-Dibrom-2,2-dichlor-aethyl)-O,O-dimethyl-phosphat O,O-二甲基-1,2-二溴-2,2-二氯代乙基磷酸酯 Dimethyl-1,2-dibromo-2,2-dichloroethyl phosphate Bromex 50 dimethyl1,2-dibromo-2,2-dichloroethylphosphate Naled Dibromfos (1,2-二溴-2,2-二氯乙基) {C BROMEX Hibrom Phosphoric Acid 1,2-Dibromo-2,2-dichloroethyl Dimethyl Ester O,O'-二甲基-1,2-二溴-2,2-二氯乙基磷酸盐 NALED Ethanol, 1,2-dibromo-2,2-dichloro-, dimethyl phosphate 1,2-Dibromo-2,2-dichloroethyl dimethyl phosphate Naledu 二溴磷 Dibrom 1,2-DIBROMO-2,2-DICHLOROETHYL DIMETHYL-PHOSPHATE O,O-Dimethyl-O-(1,2-dibromo-2,2-dichloroethyl)phosphate bromex(insecticide) Phosphate de O,O-dimethyle et de O-(1,2-dibromo-2,2-dichlorethyle) Dimethyl 1,2-dibromo-2,2-dichloroethyl phosphate 二溴磷乳油 O,O'-DIMETHYL-1,2- O-(1,2-Dibroom-2,2-dichloor-ethyl)-O,O-dimethyl-fosfaat Fosforan O-1,2-dwubromo-2,2-dwuchloroetylo-O,O-dwumetylowy Arthodibrom Bromchlophos {Chemic Alvora 1,2-Dibromo-2,2-dichloroethyl dimethyl phosphatic acid OMS 75
MDL NumberMFCD00053227
PubChem Substance ID24868564
Beilstein Registry Number2049930
EC Number206-098-3
Chemical Name Translation二溴磷
Merck Number13,6384
Wiswesser Line NotationGXGEYEOPO&O1&O1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Acaricides, All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, D, DIA - DIC, Environmental Standards,
  • {SNA} Analytical Standards, D, Insecticides, Organophorous, Organophosphate, Pesticide Class, 农残和代谢标准品, 农残,疑似对蜜蜂有害, 分析/色谱, 按照字母排序
  • {SNA} Analytical Standards,
  • Aliphatics
  • Phosphorylating and Phosphitylating Agents
  • {SNA} Acaricides, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, D,

产品应用

  • 该品是一种内吸性的杀虫杀螨剂,具有触杀、胃毒作用,并有一定的熏蒸作用。雄大鼠口服LD50为250mg/kg

相关文献及参考

  • Gaines, T.B., et al.: Toxicol. Appl. Pharmacol., 14, 515 (1969),

安全信息

RTECSTB9450000
GHS Symbol
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P301+P310+P330
  • P337+P313
  • P302+P352+P312
Hazard statements
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H319 Causes serious eye irritation 严重刺激眼睛
WGK Germany3
Signal word Danger Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Hazard Codes T,N Xn,N
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
Storage condition 储存温度2-8°C 0-6°C
UN Number 3018
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 800 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   WRPCA2 World Review of Pest Control.  (London, UK)  V.1-10, 1962-71.
   Discontinued.  Volume(issue)/page/year: 9,119,1970

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED

T

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 430 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HPBIA9 Herba Polonica.  (Ars Polona, POB 1001, 00-068 Warsaw 1, Poland)
   V.11-    1965-  Volume(issue)/page/year: 21,53,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 84 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,56,1982

TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >1500 mg/m3/6H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd,
   eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year:
   A289,1983

TYPE

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 9800 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 28,405,1975

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 300 ug/plate
REFERENCE :
   JAFCAU Journal of Agricultural and Food Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC
   20037)  V.1-    1953-  Volume(issue)/page/year: 29,268,1981

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 50 ug/plate
REFERENCE :
   JAFCAU Journal of Agricultural and Food Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC
   20037)  V.1-    1953-  Volume(issue)/page/year: 29,268,1981

其他信息

  • 外观性质:白色结晶固体或无色粘稠油状液体, 微有臭味。
  • 图谱信息:二溴磷(300-76-5)核磁图( 1 HNMR) 二溴磷(300-76-5)红外图谱(IR1) 二溴磷(300-76-5)质谱(MS) 二溴磷(300-76-5)核磁图( 13 CNMR)
  • 生产方法:将232.6g敌敌畏、0.4g过氧化苯甲酰加入四氯化碳中,搅拌加热到80℃,再滴加溴素179.4℃g。加毕,保持80℃继续反应。反应结束后,冷却,减压脱除四氯化碳即得二溴磷。
  • HazardClass:6.1(a)
  • 溶于苯、酮、醇、醚,在脂肪烃中仅溶1%,不溶于水,稍有辛辣气味
  • MOL 文件:300-76-5.mol
  • RTECS号:TB9450000
  • 用途:属速效、触杀性和胃毒性杀虫剂和杀螨剂,用于防治将要采收的蔬菜、果树等作物的害虫
  • PackingGroup:I

系列性分类


相关产品推荐