(2-Carboxyethyl)Triphenylphosphonium Tribromide （2－羧乙基）三苯基三溴化鏻
CAS 55985-85-8 MFCD00051883
化学结构图
SMILES: [Br-].OC(=O)CC[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.BrBr
化学属性
| Mol. Formula | HO2CCH2CH2P(C6H5)3Br3 |
|---|---|
| Mol. Weight | 575.09 |
| Melting Point | ca 159° dec. |
| TSCA | No |
别名和识别编码
| Chemical Name | (2-Carboxyethyl)Triphenylphosphonium Tribromide |
|---|---|
| MDL Number | MFCD00051883 |
| CAS Number | 55985-85-8 |
| Beilstein Registry Number | 6262851 |
| Chemical Name Translation | （2－羧乙基）三苯基三溴化鏻 |
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相关文献及参考
- Reagent for ɑ-bromination of ketones. Unsaturated ketones can be selectivelyɑ-brominated in high yield without bromination of the olefinic double bond: Tetrahedron Lett., 373 (1975); Synth. Commun., 19, 1091 (1989). See also 2-Pyrrolidinone hydrotribromide, L00177 for similar reagent.
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
