4-Bromo-2,6-di-tert-butylphenol 4-溴-2,6-二叔丁基苯酚

CAS 1139-52-2 MFCD00051598

化学结构图

1139-52-2
SMILES: CC(C)(C)c1cc(Br)cc(C(C)(C)C)c1O

化学属性

Mol. FormulaC14H21BrO
Mol. Weight285.22
Melting Point78-83 °C
Density1.422
TSCANo
Boiling Point128 °C at 4 mmHg

别名和识别编码

Chemical Name4-Bromo-2,6-di-tert-butylphenol
Beilstein Registry Number2051052
PubChem Substance ID70829
CAS Number1139-52-2
EC Number214-521-8
MDL NumberMFCD00051598
Reaxys-RN2051052
Synonym 4-Bromo-2,6-di-tert-butylphenol {LY} 4-Bromo-2,6-di-tert-butylphenol {} {LY} 4-Bromo-2,6-di-tert-butylphenol {} {} {LY} 4-Bromo-2,6-di-tert-butylphenol {} {} {} {LY} 4-Bromo-2,6-di-tert-butylphenol {} {} {} {} {LY} 4-Bromo-2,6-di-tert-butylphenol {} {} {} {} {} {LY} 4-Bromo-2,6-di-tert-butylphenol {} {} {} {} {} {} {LY} 4-Bromo-2,6-di-tert-butylphenol {} {} {} {} {} {} {} {LY} 4-Bromo-2,6-di-tert-butylphenol {} {} {} {} {} {} {} {} {LY} 4-Bromo-2,6-di-tert-butylphenol {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2,6-di-tert-butylphenol {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2,6-di-tert-butylphenol {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2,6-di-tert-butylphenol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2,6-di-tert-butylphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2,6-di-tert-butylphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromo-2,6-di-tert-butyl
Chemical Name Translation4-溴-2,6-二叔丁基苯酚
InChIKeySSQQUEKFNSJLKX-UHFFFAOYSA-N
LabNetwork Molecule IDLN00225359
Canonical SMILESCC(C)(C)C1=C(C(=CC(=C1)Br)C(C)(C)C)O
InChIInChI=1S/C14H21BrO/c1-13(2,3)10-7-9(15)8-11(12(10)16)14(4,5)6/h7-8,16H,1-6H3
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分类

  • {SA} Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; alcohol; 1fragment
  • Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols

相关文献及参考

  • Short: III/35D2
  • Reaction with trimethylaluminum gives the methylaluminum bis(aryloxide) which is a useful catalyst for the rearrangement of epoxides to aldehydes: Org. Synth. Coll., 9, 356 (1998).

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition RT, stored under nitrogen {LY} RT, stored under nitrogen {} {LY} RT, stored under nitrogen {} {} {LY} RT, stored under nitrogen {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • MOL 文件:1139-52-2.mol
  • Alfa Aesar:4-溴-2,6-二-叔-丁基苯酚,98% 4-Bromo-2,6-di-tert-butylphenol, 98%(1139-52-2)
  • TCI Shanghai:4-溴-2,6-二叔丁基苯酚 4-Bromo-2,6-di-tert-butylphenol,>;98.0%(GC)(1139-52-2)
  • MSDS 信息:4-Bromo-2,6-di-tert-butylphenol(1139-52-2).msds
  • Sigma Aldrich:1139-52-2(sigmaaldrich)
  • Hazard Note:Irritant
  • 4-溴-2,6-二叔丁基苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 B1758 4-溴-2,6-二-叔丁基苯酚 4-Bromo-2,6-di-tert-butylphenol 25G 807元 2010/05/25 A13876 4-溴-2,6-二-叔-丁基苯酚, 98% 4-Bromo-2,6-di-tert-butylphenol, 98% 500g 4620元 2010/05/25 A13876 4-溴-2,6-二-叔-丁基苯酚, 98% 4-Bromo-2,6-di-tert-butylphenol, 98% 25g 364元
  • 4-溴-2,6-二叔丁基苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1758 4-溴-2,6-二-叔丁基苯酚 4-Bromo-2,6-di-tert-butylphenol 25G 448元 2010/05/25 A13876 4-溴-2,6-二-叔-丁基苯酚, 98% 4-Bromo-2,6-di-tert-butylphenol, 98% 500g 4620元 2010/05/25 A13876 4-溴-2,6-二-叔-丁基苯酚, 98% 4-Bromo-2,6-di-tert-butylphenol, 98% 25g 364元
  • 图谱信息:4-溴-2,6-二叔丁基苯酚(1139-52-2)质谱(MS)

系列性分类


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