CAS 1129-28-8 MFCD00051437-Methyl 3-(bromomethyl)benzoate 3-(溴甲基)苯甲酸甲酯 TAO{mole}

Methyl 3-(bromomethyl)benzoate 3-(溴甲基)苯甲酸甲酯

CAS 1129-28-8 MFCD00051437

化学结构图

SMILES: COC(=O)c1cccc(CBr)c1

化学属性

Mol. Formula	C9H9BrO2
Mol. Weight	229
Density	1.422
Melting Point	41-45
TSCA	No
Boiling Point	112-114
Flash Point	115°C/0.8mm

别名和识别编码

Chemical Name	Methyl 3-(bromomethyl)benzoate
CAS Number	1129-28-8
Alfabeta Name	METHYLBROMOMETHYLBENZOATE 3()-
MDL Number	MFCD00051437
EC Number	419-100-4
Beilstein Registry Number	638569
Synonym	3-(BROMOMETHYL)BENZOIC ACID METHYL ESTER 3-(Bromomethyl)benzoic acid methyl ester 3-(溴甲基)苯甲酸甲酯 3-CARBOMETHOXYBENZYL BROMIDE 3-溴苯甲酸甲酯 METHYL ALPHA-BROMO-M-TOLUATE 间溴甲基苯甲酸甲酯
PubChem Substance ID	87565078
Reaxys-RN	638569
Chemical Name Translation	3-(溴甲基)苯甲酸甲酯
LabNetwork Molecule ID	LN00003228

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安全信息

Warnings IRRITANT

Signal word Danger

GHS Symbol

WGK Germany2

Safety Statements

S20 When using do not eat or drink 使用时，不得进食，饮水；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；

Risk Statements

R22 Harmful if swallowed 吞咽有害
R34 Causes burns 会导致灼伤
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应

Precautionary statements

P234 Keep only in original container. 只保留在原来的容器中。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331
P301+P330+P331+P310
P303+P361+P353+P310+P363
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
P405 Store locked up. 上锁保管。
P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Packing GroupII

UN Number 3261 UN 3261 8/PG 2

Hazard statements

H290 May be corrosive to metals 可能腐蚀金属。
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H302 Harmful if swallowed 吞食有害

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Hazard Codes 8 C C,Xi

Storage condition 储存温度2-8°C

Hazard Class8

其他信息

F:19
Acros Organics:3-(溴甲基)苯甲酸甲酯 Methyl 3-(bromomethyl)benzoate, 95%(1129-28-8)
MSDS 信息:Methyl 3-(bromomethyl)benzoate(1129-28-8).msds
Alfa Aesar:3-(溴甲基)苯甲酸甲酯,97% Methyl 3-(bromomethyl)benzoate, 97%(1129-28-8)
上游原料:石油醚 --> 四氯化碳 --> N-溴代丁二酰亚胺 --> 过氧化二苯甲酰 --> 3-甲基苯甲酸甲酯
TCI Shanghai:3-(溴甲基)苯甲酸甲酯 Methyl 3-(Bromomethyl)benzoate,>;97.0%(GC)(1129-28-8)
MOL 文件:1129-28-8.mol
存储注意事项:光敏感;氮气保护;热敏感
检测方法:HPLC
3-溴甲基苯甲酸甲酯价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 B2224 3-(溴甲基)苯甲酸甲酯 Methyl 3-(Bromomethyl)benzoate 25G 2240元 2014/06/02 B2224 3-(溴甲基)苯甲酸甲酯 Methyl 3-(Bromomethyl)benzoate 5G 657元 2010/06/21 TL00214EA 3-溴甲基苯甲酸甲酯 methyl 3-(bromomethyl)benzoate 10 GR 1110元
图谱信息:3-溴甲基苯甲酸甲酯(1129-28-8)红外图谱(IR1) 3-溴甲基苯甲酸甲酯(1129-28-8)红外图谱(IR2) 3-溴甲基苯甲酸甲酯(1129-28-8)质谱(MS)
Sigma Aldrich:1129-28-8(sigmaaldrich)
下游产品:3-氨甲基苯甲酸甲酯盐酸盐
Hazard Note:Irritant/Corrosive