CAS 866-82-0 MFCD00050820-Cupric Citrate 柠檬酸铜 TAO{mole}

Cupric Citrate 柠檬酸铜

CAS 866-82-0 MFCD00050820

化学结构图

SMILES: O=C([O-])CC(O)(CC(=O)[O-])C(=O)[O-].O=C([O-])CC(O)(CC(=O)[O-])C(=O)[O-].[Cu+2].[Cu+2].[Cu+2]

化学属性

Mol. Formula	C12H10Cu3O14
Mol. Weight	568.84
Appearance	蓝绿色粉末。微溶于水、冷的柠檬酸钠溶液，溶于氨水、酸和热的硫酸铜溶液与适量柠檬酸钠溶液作用而得。
Melting Point	239-244 °C

别名和识别编码

Chemical Name	Cupric Citrate
CAS Number	866-82-0
Synonym	Copper citrate {LY} Copper citrate {} {LY} Copper citrate {} {} {LY} Copper citrate {} {} {} {LY} Copper citrate {} {} {} {} {LY} Copper citrate {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper citrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number	212-752-9
MDL Number	MFCD00050820
Chemical Name Translation	柠檬酸铜
Wiswesser Line Notation	OV1XO&VO&1VO &-CU- 2
PubChem Substance ID	120942
InChI	InChI=1S/C6H8O7.2Cu/c7-3(8)1-6(13,5(11)12)2-4(9)10;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);;/q;2*+2
Canonical SMILES	OC(C([O-])=O)(CC([O-])=O)CC([O-])=O.OC(C([O-])=O)(CC([O-])=O)CC([O-])=O.[Cu+2].[Cu+2].[Cu+2]

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安全信息

RTECSGL7056000

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1580 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   MarJV# Personal Communication from J.V. Marhold, VUOS, 539-18, Pardubice,
   Czechoslavakia, Mar. 29, 1977  Volume(issue)/page/year: 29MAR1977

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - hamster
DOSE                    : 1800 ug/kg
SEX/DURATION            : female 8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   BIREBV Biology of Reproduction.  (Soc. for the Study of Reproduction, 309 W.
   Clark St., Champaign, IL 61820)  V.1-    1969-  Volume(issue)/page/year:
   11,97,1974

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - hamster
DOSE                    : 2700 ug/kg
SEX/DURATION            : female 8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - cardiovascular
   (circulatory) system
   Reproductive - Specific Developmental Abnormalities - homeostasis
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 21,89,1980

Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store

其他信息

MOL 文件:866-82-0.mol
中毒症状:误食引起急性中毒，表现为头痛、头晕、乏力、口腔粘膜呈蓝色，口内有金属味，齿龈，舌发青，腹泻，腹绞痛，黑大便，重者昏迷、痉挛，血压下降等。
储运特性:库房低温, 通风, 干燥
类别:农药
毒性分级:中毒
图谱信息:枸橼酸铜(866-82-0)红外图谱(IR1) 枸橼酸铜(866-82-0)红外图谱(IR2)
急救治疗:经口中毒，立即催吐、洗胃。解毒剂为依地酸二钠钙，并配合对症治疗。
急性毒性:口服- 大鼠 LD50: 1580 毫克/ 公斤
灭火剂:水, 二氧化碳, 干粉, 砂土
注意事项:在我国未登记。
可燃性危险特性:不可燃烧; 火场产生有毒含铜化物烟雾;
用途二:用作分析试剂及防腐剂
用途一:用作防腐剂、杀虫剂、收敛剂等