CAS 107-71-1 MFCD00048240-T-Butyl Peroxyacetate 过氧化乙酸叔丁酯 TAO{mole}

T-Butyl Peroxyacetate 过氧化乙酸叔丁酯

CAS 107-71-1 MFCD00048240

化学结构图

SMILES: CC(=O)OOC(C)(C)C

化学属性

Mol. Formula	CH3CO3C(CH3)3
Mol. Weight	132
Refractive index	n20/D 1.412
Density	0.828
Flash Point	99 °F
Melting Point	-20 °C
Solubility	不溶于水，溶于多数有机溶剂。

别名和识别编码

Chemical Name	T-Butyl Peroxyacetate
CAS Number	107-71-1
PubChem Substance ID	61019
MDL Number	MFCD00048240
EC Number	203-514-5
Beilstein Registry Number	1701510
Synonym	peroxyacetic acid tert-butyl ester T-BUTYL PERACETATE Peroxyacetic acid, tert-butyl ester LUPEROX 7M75 Perbutyl A TERT-BUTYL PERACETATE Trigonox® F 过乙酸特丁酯 tert-Butyl peracetate 过氧化乙酸叔丁酯 trigonoxf-c50 Ethaneperoxoicacid,1,1-dimethylethylester tert.-Butylperoxyacetat Kayabutyl A 50T lupersol70 t-Butylethaneperoxoicacid Peroxyessigsäure-tert.-butylester LUPEROX 7M50 tert-Butyl peracetate solution Trigonox?F Ethaneperoxoic acid tert-butyl ester tert-Butyl peroxylacetate Trigonox F 过氧乙酸叔丁酯溶液 tert-butyl Esperox 12MD
Chemical Name Translation	过氧化乙酸叔丁酯
Wiswesser Line Notation	1X1&1&OOV1
InChI	InChI=1S/C6H12O3/c1-5(7)8-9-6(2,3)4/h1-4H3

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安全信息

GHS Symbol

WGK Germany3

Hazard Codes O,T

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
H302 Harmful if swallowed 吞食有害
H335 May cause respiratory irritation 可能导致呼吸道刺激
H242 Heating may cause a fire 加热可能会引起火灾
H340 May cause genetic defects 可能导致遗传性缺陷
H319 Causes serious eye irritation 严重刺激眼睛
H350 May cause cancer 可能致癌
H226 Flammable liquid and vapour 易燃液体和蒸气
H331 Toxic if inhaled 吸入中毒
H241 Heating may cause a fire or explosion 加热可能会引起火灾或爆炸

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P301+P310
P201 Obtain special instructions before use. 使用前获取专门指示。
P308+P313
P304+P340+P312
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P370+P378

Signal word

Safety Statements

S3/7 Keep container tightly closed in a cool place 将容器严格密闭保存在阴凉处；
S7 Keep container tightly closed 保存在严格密闭容器中；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
S14 Keep away from ... (incompatible materials to be indicated by the manufacturer) 远离（生产厂家指定的不相容物质）保存；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S47 Keep at temperature not exceeding ... °C (to be specified by the manufacturer) 保持温度不超过……°C（由生产厂家指定）；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Risk Statements

R10 Flammable 易燃
R22 Harmful if swallowed 吞咽有害
R46 May cause inheritable genetic damage 可能引起遗传基因损害
R45 May cause cancer 可能致癌
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
R7 May cause fire 会导致起火
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用

Packing GroupII

Hazard Class5.2

Storage condition Refrigerator (+4°C) + Flammables area

UN Number UN 3103 5.2

RTECSSD8925000

Warnings 危化品目录(2015)

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 632 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv.
   Toxicology of New Industrial Chemical Substances.  For English translation,
   see TNICS*.  (Izdatel'stvo Meditsina, Moscow, USSR)  No.1-    1961-
   Volume(issue)/page/year: 9,78,1967

TYPE OF TEST            : LC33 - Lethal Concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8200 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,30,1982

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 6000 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv.
   Toxicology of New Industrial Chemical Substances.  For English translation,
   see TNICS*.  (Izdatel'stvo Meditsina, Moscow, USSR)  No.1-    1961-
   Volume(issue)/page/year: 9,78,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 675 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izm

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1 mg/m3/4H
SEX/DURATION            : male 17 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
REFERENCE :
   TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv.
   Toxicology of New Industrial Chemical Substances.  For English translation,
   see TNICS*.  (Izdatel'stvo Meditsina, Moscow, USSR)  No.1-    1961-
   Volume(issue)/page/year: 10,44,1968

Restrict 危险品

其他信息

类别:氧化剂
MSDS 信息:过乙酸特丁酯(107-71-1).msds
下游产品:
毒性分级:中毒
职业标准:STEL 0.1 毫克/立方米
Acros Organics:过氧化乙酸叔丁酯 tert-Butyl peroxyacetate, 50% solution in aromatic free mineral spirit(107-71-1)
过氧化乙酸叔丁酯价格(试剂级):更新日期产品编号产品名称包装价格 2010/06/21 349860100 过氧化乙酸叔丁酯 tert-Butyl peroxyacetate , 50% solution in aromatic free mineral spirit 10 ML 339元 2010/06/21 349862500 过氧化乙酸叔丁酯 tert-Butyl peroxyacetate , 50% solution in aromatic free mineral spirit 250 ML 581元
灭火剂:水、干粉、二氧化碳, 泡沫
刺激数据:眼睛-兔子 100 毫克/1 分中度
Sigma Aldrich:107-71-1(sigmaaldrich)
储运特性:库房通风低温干燥; 与有机物、还原物、易燃物、强酸分开存放
方法一:用叔丁醇以过氧化氢氧化，生成叔丁基过氧化氢，然后与乙酸酐反应制得该品。
外观性质:无色透明苯或矿油溶液。
急性毒性:口服-大鼠 LD50: 675 毫克/公斤; 口服-小鼠 LD50: 532 毫克/公斤
爆炸物危险特性:遇热分解易爆; 热, 震动灵敏爆炸
MOL 文件:107-71-1.mol
上游原料:过氧化氢 --> 叔丁基过氧化氢
用途一:氟呋尿嘧啶的中间体，也可作氧化剂，聚合反应引发剂。
可燃性危险特性:遇还原剂、铵、有机物、酸、易燃物混合易燃; 热分解分解排出辛辣刺激烟雾