CAS 139-40-2 MFCD00047341-6-Chloro-N2,N4-diisopropyl-1,3,5-triazine-2,4-diamine N/A TAO{mole}

6-Chloro-N2,N4-diisopropyl-1,3,5-triazine-2,4-diamine N/A

CAS 139-40-2 MFCD00047341

化学结构图

SMILES: CC(C)Nc1nc(Cl)nc(NC(C)C)n1

化学属性

Mol. Formula	C9H16ClN5
Mol. Weight	229.71
Melting Point	212-214 °C
Density	1.162
Flash Point	11°C
Solubility	微溶于水。
Boiling Point	368.7 °C at 760 mmHg

别名和识别编码

Chemical Name	6-Chloro-N2,N4-diisopropyl-1,3,5-triazine-2,4-diamine
Synonym	Propazine {LY} Propazine {} {LY} Propazine {} {} {LY} Propazine {} {} {} {LY} Propazine {} {} {} {} {LY} Propazine {} {} {} {} {} {LY} Propazine {} {} {} {} {} {} {LY} Propazine {} {} {} {} {} {} {} {LY} Propazine {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} Propazine {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} Propazine {} {} {} {} {} {} {} {} {} {} {LY} Propazine {} {} {} {} {} {} {} {} {} {} {} {LY} Propazine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Propazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Propazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Propazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Propazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Propazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Propazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL Number	MFCD00047341
CAS Number	139-40-2
PubChem Substance ID	4937
Beilstein Registry Number	0747081
EC Number	205-359-9
Chemical Name Translation	N/A
Merck Number	13,7904
Wiswesser Line Notation	T6N CN ENJ BMY DMY FG
InChI	InChI=1S/C9H16ClN5/c1-5(2)11-8-13-7(10)14-9(15-8)12-6(3)4/h5-6H,1-4H3,(H2,11,12,13,14,15)
Canonical SMILES	ClC1=NC(NC(C)C)=NC(NC(C)C)=N1

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产品应用

扑灭津系选择性三嗪类除草剂，芽前用于防除高粱和伞形花科作物田中阔叶和禾本科杂草

安全信息

RTECSXY5300000

GHS Symbol

Precautionary statements

P501 Dispose of contents/container to..… 处理内容物/容器.....
P273 Avoid release to the environment. 避免释放到环境中。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P301+P310
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。

Hazard statements

H370 Causes damage to organs 导致器官损伤
H331 Toxic if inhaled 吸入中毒
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H301 Toxic if swallowed 吞食有毒
H311 Toxic in contact with skin 皮肤接触中毒
H351 Suspected of causing cancer 怀疑致癌
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。

WGK Germany3

Signal word Danger Warning

Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)

Hazard Codes F,T Xn;N Xn;N,N,Xn,T,F Xn,N

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S7 Keep container tightly closed 保存在严格密闭容器中；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S24 Avoid contact with skin 避免皮肤接触；

Risk Statements

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R11 Highly flammable 非常易燃
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R50/53
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险

UN Number 3077 UN 3077

Storage condition APPROX 4°C 室温储存

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 11 gm/kg/78W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Blood - tumors
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB223-159

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,35,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >3100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PEMNDP Pesticide Manual.  (The British Crop Protection Council, 20 Bridport
   Rd., Thornton Heath CR4 7QG, UK)  V.1-    1968-  Volume(issue)/page/year:
   9,721,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >10200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CIGET* Ciba-Geigy Toxicology Data/Indexes.  (Ciba-Geigy Corp., 556 Morris
   Ave., Summit, NJ 07901)  Volume(issue)/page/year: -,-,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 395 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FATOAO Farmakologiya i Toksikologiya (Moscow).  For English translation, see
   PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2-   
   1939-  Volume(issue)/page/year: 42,163,1979

TYPE OF TEST            : LD50 - Lethal dos

其他信息

用途二:扑灭津系选择性三嗪类除草剂，芽前用于防除高粱和伞形花科作物田中阔叶和禾本科杂草，用量0.5-3.0 kg(a.i.)/hm2。
作用方式、机理:扑灭津为选择性内吸传导型土壤处理除草剂，作用机理与西玛津相似内吸作用比西玛津迅速，在土壤中的移动性也比西玛津大。有一定的触杀作用。本条信息由Chemicalbook晓楠编辑整理。
MSDS 信息:扑草津(139-40-2).msds
MOL 文件:139-40-2.mol
毒性:对大鼠的急性口服LD50>7g/kg。急性经皮LD50：大鼠>3.1g/kg，兔>10.2g/kg。对兔皮肤和眼睛有轻微刺激。兔急性吸入LC50(4小时)>2.04mg/ L空气。在130天饲喂试验中，以250mg/kg饲料对雌、雄大鼠无影响。90天饲养无作用剂量(WP 800g ai/kg)：大鼠200mg ai/kg饲料[13mg/(kg·d)]，狗200mg ai/kg饲料[7mg/(kg ·d)]。鹌鹑和野鸭LC50 (8天)>10g/kg。鱼毒LC50(96小时)：虹鳟17.5mg/ L，蓝鳃>100mg/L，金鱼>32.0mg/L。对蜜蜂无毒。
杀虫剂单一组分标准液
外观性质:无色结晶固体。
中性、弱酸或弱碱性介质中稳定，在较强酸碱中可水解成无除草性能的羟基衍生物，温度越高水解越快，无腐蚀性
开发单位:1957年由H.Gysin等报道除草活性，1958年瑞士Ciba—Geigy Ltd.开发，1960 年由J.R.Geigy S.A.(现为Novartis Crop Protection AG，不再生产和销售)推广，获有专利Swiss P 329277；BP 814947；US 2891855；BE 540947。
分析方法:1. 用吗啉处理后，则定放出的HCl量； 2. 用高氯酸进行电位滴定。
Sigma Aldrich:139-40-2(sigmaaldrich)
用途一:除草剂，适用于谷子、玉米、高粱、甘蔗、芹菜、豌豆等作物
下游产品:扑草净 --> 异丙净 --> 氟草净
残留量测定:1. 将扑灭净转反应为羟基衍生物后进行紫外吸收； 2. 薄层色谱法和气相色谱法。
防除对象:一年生禾本科杂草和阔叶杂草。对双子叶杂草的杀伤力大于单子叶杂草。对一些多年生的杂草也有一定的杀伤力，扑灭津对刚萌发的杂草防除效果显著，对较大的杂草及多年生深根性杂草效果较差。
制备方法:在缚酸剂存在下，由三聚氯氰与两个当量的异丙胺反应制得扑灭津。图2为制备扑灭津的化学反应路线图。
使用方法:在玉米、谷子、高粱地使用，于播种后3—5 天，每公顷用50%扑灭津3—6kg对水喷雾作土壤处理。苗圃杂草可作茎叶处理，每公顷用50%扑灭津1.5— 7.5kg用于马尾松苗，0.75—1.5用于梧桐苗，对水喷雾。
适用作物:谷子、玉米、高粱、甘蔗、胡萝卜、芹菜、豌豆等。
除草剂:三氮苯类内吸、选择性除草剂。化学名称：2-氯-4，6-双异丙胺基-1，3，5-三氮苯。纯品无色结晶，熔点为212～214℃，20℃时蒸气压为386.6×10-8 Pa。几乎不溶于水，难溶于有机溶剂，但能从2—乙氧基乙醇和二甲基甲酰胺中重结晶。工业品纯度大于95%，在中性、弱酸或弱碱溶液中稳定，遇强酸、强碱易分解。可通过根系吸收，并传导到叶片，抑制光合作用的希尔反应，使叶片缺绿，植株饥饿死亡。可用于玉米、高粱、谷子、果园和苗圃，防除马唐、狗尾草、稗草、早熟禾、看麦娘、藜蓼、繁缕、荠菜等杂草。在土壤中残留期长，对后茬敏感作物易发生药害。对人、畜低毒，大鼠急性口服LD50>5000mg/kg，兔急性经皮LD50>10200mg/kg。图1为扑灭津结构式。