Ethylaluminum sesquichloride solution 三氯三乙基络铝
CAS 12075-68-2 MFCD00044852
化学结构图
SMILES: CC[Al](Cl)Cl.CC[Al](Cl)CC
化学属性
| Mol. Formula | C6H15Al2Cl3 |
|---|---|
| Mol. Weight | 247.52 |
| Boiling Point | 204°C |
| Density | 0.701 |
| Melting Point | -50°C |
| Flash Point | -18 ºC |
别名和识别编码
| Chemical Name | Ethylaluminum sesquichloride solution |
|---|---|
| PubChem Substance ID | 24855562 |
| EC Number | 235-137-7 |
| Beilstein Registry Number | 4027369 |
| MDL Number | MFCD00044852 |
| CAS Number | 12075-68-2 |
| Synonym | Trichlorotriethyldialuminium Triethyltrichlorodialuminum 倍半乙基氯化铝 Sesquiethylaluminum chloride 乙基倍半铝氯化物; 倍半乙基氯化铝 Ethylaluminum sesquichloride 三氯三乙基络铝,乙基三氯化二铝,乙基倍半氯化铝 三氯三乙基络铝 Triethyldialuminum trichloride Triethylaluminum sesquichloride Trichlorotriethyldialuminum |
| Chemical Name Translation | 三氯三乙基络铝 |
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分类
- {SNA} Chemical Synthesis, Organoaluminum, Organometallic Reagents
产品应用
- 聚烯烃工业的催化剂，制造有机化合物的中间体。
安全信息
GHS Symbol
- H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
- H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P273 Avoid release to the environment. 避免释放到环境中。
- P281 Use personal protective equipment as required. 使用所需的个人防护装备。
- P301+P310
- P302+P352
- P331 Do NOT induce vomiting.. 不要催吐。
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S29 Do not empty into drains 不要排入下水道；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
- S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中；
- R11 Highly flammable 非常易燃
- R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
- R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
- R17 Spontaneously flammable in air 在空气中能够自燃
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
- R34 Causes burns 会导致灼伤
- R35 Causes severe burns 会导致严重灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R48/20
- R51/53
- R62 Possible risk of impaired fertility 有削弱生殖能力的危险
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
其他信息
- 和水剧烈反应，与饱和脂肪族烃和芳香族烃混溶。
