2-Butanone Peroxide 2-过氧化丁酮
CAS 1338-23-4 MFCD00042641
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Chemical Synthesis, Free Radical Initiators, Organic Peroxides, Oxidizing Agents, Peroxides, Polymer Science, Polymerization Initiators, Reagents for Polymerization, Synthetic Reagents, 材料科学
- {SNA} Chemical Synthesis, Oxidizing Agents, Peroxides, Synthetic Reagents
- {SNA} Chemical Synthesis, Free Radical Initiators, Materials Science, Organic Peroxides, Oxidizing Agents, Peroxides, Polymer Science, Polymerization Initiators, Reagents for Polymerization, Synthetic Reagents
- Chemical Synthesis, Free Radical Initiators, Materials Scie
产品应用
- 不饱和聚酯树脂常温固化引发剂。
相关文献及参考
- Beil. 1 ,IV,3249
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H242 Heating may cause a fire 加热可能会引起火灾
- H302 Harmful if swallowed 吞食有害
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
- P233 Keep container tightly closed. ?保持容器密闭。
- P234 Keep only in original container. 只保留在原来的容器中。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P301+P312+P330
- P302+P352+P332+P313+P362+P364
- P303+P361+P353
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P308+P311
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
- P403+
- P403+P233
- P403+P235
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P410 Protect from sunlight. 防止阳光照射。
- P411+P235
- P420 Store away from other materials. 远离其他材料。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S14 Keep away from ... (incompatible materials to be indicated by the manufacturer) 远离(生产厂家指定的不相容物质)保存;
- S3/7 Keep container tightly closed in a cool place 将容器严格密闭保存在阴凉处;
- S7 Keep container tightly closed 保存在严格密闭容器中;
- S17 Keep away from combustible material 远离可燃物料;
- S47 Keep at temperature not exceeding ... °C (to be specified by the manufacturer) 保持温度不超过……°C(由生产厂家指定);
- S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
- R34 Causes burns 会导致灼伤
- R7 May cause fire 会导致起火
- R22 Harmful if swallowed 吞咽有害
- R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
- R9 Explosive when mixed with combustible material 与易燃物混合会爆炸
- R38 Irritating to skin 刺激皮肤
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R35 Causes severe burns 会导致严重灼伤
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
- R23 Toxic by inhalation 吸入有毒
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Unreported SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 282 mg/kg TOXIC EFFECTS : Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors Blood - lymphoma, including Hodgkin's disease REFERENCE : RARSAM Radiation Research, Supplement. (New York, NY) No.1-7, 1959-67. Discontinued. Volume(issue)/page/year: 3,193,1963
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 65 mg/kg TOXIC EFFECTS : Behavioral - muscle weakness Behavioral - ataxia REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 19,205,1958
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Ora
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Human DOSE/DURATION : 480 mg/kg TOXIC EFFECTS : Gastrointestinal - changes in structure or function of esophagus Gastrointestinal - nausea or vomiting Gastrointestinal - other changes REFERENCE : NCPBBY National Clearinghouse for Poison Control Centers, Bulletin. (U.S. Department of Health, Education, and Welfare, Washington, DC) Volume(issue)/page/year: Jan/Feb,1969
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 200 ppm/4H TOXIC EFFECTS : Lungs, Thorax, or Respiration - dyspnea REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 19,205,1958
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 170 ppm/4H TOXIC EFFECTS : Lungs, Thorax, or Respiration - dyspnea REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 19,205,1958
{hazard
其他信息
- 类别:氧化剂
- 上游原料:过氧化氢 --> 磷酸 --> 2-丁酮 --> 邻苯二甲酸二丁酯 --> 酞酸二甲酯 --> 增溶剂 --> 过氧化氢(双氧水)
- 下游产品:树脂,玻璃布
- MOL 文件:1338-23-4.mol
- 可燃性危险特性:高温可燃; 燃烧产生刺激烟雾
- 储运特性:库房通风低温; 轻装轻卸; 与有机物、还原剂、硫、磷易燃物, 食品原料分开存放
- 过氧化丁酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K0439001 过氧化-2-丁酮 100ml 514元
- 用途三:不饱和聚酯树脂常温固化引发剂。
- 毒性分级:高毒
- 用途二:在聚酯及丙烯酸系聚合物生产中用作催化剂,是最安全的过氧化物。还广泛用于强化聚酯玻璃纤维生产作硬化剂。
- 急性毒性:口服- 大鼠 LD50: 484 毫克/ 公斤; 口服- 小鼠 LD50: 470 毫克/ 公斤
- 方法一:在硫酸存在下,由甲乙酮与过氧化氢(双氧水)反应制取。经氧化、中和、分离、脱水、静置、过滤,最后加入增溶剂而得成品。
- 爆炸物危险特性:与还原剂、硫、磷等混合可爆; 摩擦、光照、受热、撞击可爆
- 外观性质:无色油状液体,有愉快的气味。
- 具有宜人气味。在室温下稳定上,当温度高于100℃时即发生爆炸。
- Sigma Aldrich:1338-23-4(sigmaaldrich)
- 职业标准:TWA 1.5 毫克/ 立方米; STEL 1 毫克/ 立方米
- 灭火剂:雾状水、砂土、二氧化碳、泡沫
- MSDS 信息:过氧化丁酮(1338-23-4).msds
- 刺激数据:皮肤- 兔子 500 毫克; 眼睛- 兔子 3 毫克
- 用途一:用作不饱和聚酯树脂的常温固化剂、有机合成的引发剂、漂白剂、杀菌剂