2-Butanone Peroxide 2-过氧化丁酮

CAS 1338-23-4 MFCD00042641

化学结构图

1338-23-4
SMILES: CCC(C)(OO)OOC(C)(CC)OO

化学属性

Mol. FormulaC2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
Mol. Weight210.22
Density0.99 g/mL at 25 °C
Refractive indexn20/D 1.437
Melting Point110 ºC
Solubility0.1-0.5 G/100 ML AT 22 ºC
Boiling Point284 °C
Flash Point50°C(lit.)

别名和识别编码

Chemical Name2-Butanone Peroxide
Synonym LUPERSOL(TM) DHD-9* 2-丁酮 过氧化物 Lupersol DSW MEK peroxide Es Luperox® DDM-30 过氧化甲乙酮 溶液 过氧化-2-丁酮 过氧化丁酮 chaloxydmekp-ha1[qr] Chaloxyd MEKP-LA 1 HI-Point 180 butanoxlpt Kayamek M ethyl methyl ketone peroxide Permek G 甲基乙基酮過氧化物 Butanox LPT chaloxydmekp-la1[qr] METHYL ETHYL KETONE PEROXIDE {Ch 2-BUTANONE PEROXIDE Lupersol DNF Luperox® DHD-9,2-过氧化丁酮 溶液 过氧化甲乙酮 溶液 MEKPO Mepox Methyl ethyl ketone hydroperoxide Sprayset MEKP NCI-C55447 RCRA waste number U160 甲基乙基酮过氧化物 LUPERSOL DELTA X-9 ethylmethylketoneperoxide[qr] LUPEROX(R) DSW-9 过氧化丁酮液 Lucidol Delta X {hazar Kayamek A HI-Point PD-1 Methylethylketonhydroperoxide 2-过氧化丁酮 溶液 Permek N Ethyl methyl ketone peroxide Luperox® DDM-9,2-过氧化丁酮 溶液 FR 222 chaloxydmekp-la1 LUPERSOL DDM-9 Chaloxyd MEKP-HA 1 Lupersol DDM 过氧化2-丁酮 过氧化甲乙酮 Ethyl methyl ketone peroxide; Methyl ethyl ketone peroxide Superox 46-710 Methyl 2-过氧化丁酮 溶液 过氧化甲乙酮 溶液 butanoxm105 催化剂糊M butanoxm50 Butanox M 50 Luci chaloxydmekp-ha1
Beilstein Registry Number1759757
PubChem Substance ID3672772
CAS Number1338-23-4
MDL NumberMFCD00042641
EC Number215-661-2
Chemical Name Translation2-过氧化丁酮
Wiswesser Line Notation1V2OO2V1
InChIInChI=1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3
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分类

  • {SNA} Chemical Synthesis, Free Radical Initiators, Organic Peroxides, Oxidizing Agents, Peroxides, Polymer Science, Polymerization Initiators, Reagents for Polymerization, Synthetic Reagents, 材料科学
  • {SNA} Chemical Synthesis, Oxidizing Agents, Peroxides, Synthetic Reagents
  • {SNA} Chemical Synthesis, Free Radical Initiators, Materials Science, Organic Peroxides, Oxidizing Agents, Peroxides, Polymer Science, Polymerization Initiators, Reagents for Polymerization, Synthetic Reagents
  • Chemical Synthesis, Free Radical Initiators, Materials Scie

产品应用

  • 不饱和聚酯树脂常温固化引发剂。

相关文献及参考

  • Beil. 1 ,IV,3249

安全信息

WGK Germany1
Hazard Codes O,Xn,C,T O;C O,C
GHS Symbol
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H242 Heating may cause a fire 加热可能会引起火灾
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P312+P330
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P403+
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P410 Protect from sunlight. 防止阳光照射。
  • P411+P235
  • P420 Store away from other materials. 远离其他材料。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S14 Keep away from ... (incompatible materials to be indicated by the manufacturer) 远离(生产厂家指定的不相容物质)保存;
  • S3/7 Keep container tightly closed in a cool place 将容器严格密闭保存在阴凉处;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
  • S17 Keep away from combustible material 远离可燃物料;
  • S47 Keep at temperature not exceeding ... °C (to be specified by the manufacturer) 保持温度不超过……°C(由生产厂家指定);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R7 May cause fire 会导致起火
  • R22 Harmful if swallowed 吞咽有害
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
  • R9 Explosive when mixed with combustible material 与易燃物混合会爆炸
  • R38 Irritating to skin 刺激皮肤
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R35 Causes severe burns 会导致严重灼伤
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R23 Toxic by inhalation 吸入有毒
UN Number 2127/2550/3105 3105 UN 3105 5.2
Packing GroupII
Hazard Class5.2
Storage condition 0-10°C 2-8°C 2-8°C保存
Warnings 危化品目录(2015)
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 282 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Blood - lymphoma, including Hodgkin's disease
REFERENCE :
   RARSAM Radiation Research, Supplement.  (New York, NY)  No.1-7, 1959-67.
   Discontinued.  Volume(issue)/page/year: 3,193,1963

RTECSEL9450000
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 65 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Behavioral - ataxia
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   19,205,1958

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Ora

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 480 mg/kg
TOXIC EFFECTS :
   Gastrointestinal - changes in structure or function of esophagus
   Gastrointestinal - nausea or vomiting
   Gastrointestinal - other changes
REFERENCE :
   NCPBBY National Clearinghouse for Poison Control Centers, Bulletin.  (U.S.
   Department of Health, Education, and Welfare, Washington, DC)
   Volume(issue)/page/year: Jan/Feb,1969

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 200 ppm/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   19,205,1958

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 170 ppm/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   19,205,1958

{hazard

其他信息

  • 类别:氧化剂
  • 上游原料:过氧化氢 --> 磷酸 --> 2-丁酮 --> 邻苯二甲酸二丁酯 --> 酞酸二甲酯 --> 增溶剂 --> 过氧化氢(双氧水)
  • 下游产品:树脂,玻璃布
  • MOL 文件:1338-23-4.mol
  • 可燃性危险特性:高温可燃; 燃烧产生刺激烟雾
  • 储运特性:库房通风低温; 轻装轻卸; 与有机物、还原剂、硫、磷易燃物, 食品原料分开存放
  • 过氧化丁酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K0439001 过氧化-2-丁酮 100ml 514元
  • 用途三:不饱和聚酯树脂常温固化引发剂。
  • 毒性分级:高毒
  • 用途二:在聚酯及丙烯酸系聚合物生产中用作催化剂,是最安全的过氧化物。还广泛用于强化聚酯玻璃纤维生产作硬化剂。
  • 急性毒性:口服- 大鼠 LD50: 484 毫克/ 公斤; 口服- 小鼠 LD50: 470 毫克/ 公斤
  • 方法一:在硫酸存在下,由甲乙酮与过氧化氢(双氧水)反应制取。经氧化、中和、分离、脱水、静置、过滤,最后加入增溶剂而得成品。
  • 爆炸物危险特性:与还原剂、硫、磷等混合可爆; 摩擦、光照、受热、撞击可爆
  • 外观性质:无色油状液体,有愉快的气味。
  • 具有宜人气味。在室温下稳定上,当温度高于100℃时即发生爆炸。
  • Sigma Aldrich:1338-23-4(sigmaaldrich)
  • 职业标准:TWA 1.5 毫克/ 立方米; STEL 1 毫克/ 立方米
  • 灭火剂:雾状水、砂土、二氧化碳、泡沫
  • MSDS 信息:过氧化丁酮(1338-23-4).msds
  • 刺激数据:皮肤- 兔子 500 毫克; 眼睛- 兔子 3 毫克
  • 用途一:用作不饱和聚酯树脂的常温固化剂、有机合成的引发剂、漂白剂、杀菌剂

系列性分类


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