p-Azidophenacyl Bromide 4-叠氮苯甲酰甲基溴
CAS 57018-46-9 MFCD00042637
化学结构图
SMILES: [N-]=[N+]=NC1C=CC(=CC=1)C(=O)CBr
化学属性
| Mol. Formula | C8H6BrN3O |
|---|---|
| Mol. Weight | 240.06 |
| Melting Point | 64-65 °C |
别名和识别编码
| Chemical Name | 4-Azidophenacyl bromide |
|---|---|
| CAS Number | 57018-46-9 |
| Synonym | 1-(4-Azidophenyl)-2-bromo-ethanone 4-叠氮苯甲酰甲基溴 4′-叠氮-2-溴苯乙酮 4-叠氮-α-溴苯乙酮 4′-叠氮-2-溴苯乙酮 4-叠氮-α-溴苯乙酮 4-叠氮-α-溴苯乙酮 4′-叠氮-2-溴苯乙酮 4'-Azido-2-bromoacetophenone |
| PubChem Substance ID | 57653867 |
| EC Number | 260-519-5 |
| Beilstein Registry Number | 1961705 |
| MDL Number | MFCD00042637 |
| Chemical Name Translation | 4-叠氮苯甲酰甲基溴 |
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分类
- {SNA} Aromatic Azides, Azides, Building Blocks, Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents,
- {SNA} Aromatic Azides, Azides, Building Blocks, Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents,
产品应用
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相关文献及参考
- Schwartz, I., et al.: Proc. Natl. Acad. Sci. USA, 71, 230 (1974)
- Hixson, S.H., et al., p-Azidophenacyl bromide, a versatile photolabile bifunctional reagent. Biochemistry 14 , 4251, (1975) 摘要
- Hu D., et al., Probing the Structure of the PI-SceI-DNA Complex by Affinity Cleavage and Affinity Photocross-linking. J. Biol. Chem. 275 , 2705, (2000) 摘要
安全信息
GHS Symbol
- H228 Flammable solid 易燃固体
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- R11 Highly flammable 非常易燃
- R42/43
- R34 Causes burns 会导致灼伤
