CAS 2210-25-5 MFCD00041913-N-Isopropylacrylamide, 98% N-异丙基丙烯酰胺 TAO{mole}

N-Isopropylacrylamide, 98% N-异丙基丙烯酰胺

CAS 2210-25-5 MFCD00041913

化学结构图

SMILES: C=CC(=O)NC(C)C

化学属性

Mol. Formula	C6H11NO
Mol. Weight	113.16
Boiling Point	225.074 °C at 760 mmHg
Melting Point	60-63°C
Density	0.98
Solubility	溶于水。
Stability	热敏感

别名和识别编码

Chemical Name	N-Isopropylacrylamide, 98%
Synonym	N-Isopropylacrylamide {LY} N-Isopropylacrylamide {} {LY} N-Isopropylacrylamide {} {} {LY} N-Isopropylacrylamide {} {} {} {LY} N-Isopropylacrylamide {} {} {} {} {LY} N-Isopropylacrylamide {} {} {} {} {} {LY} N-Isopropylacrylamide {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Isopropylacrylamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Isopropylacrylamide {} {} {} {} {} {} {} {} {LY} N-Isopropylacrylamide {} {} {} {} {} {} {} {} {} {LY} N-Isopropylacrylamide {} {} {} {} {} {} {} {} {} {} {LY} N-Isopropylacrylamide {} {} {} {} {} {} {} {} {} {} {} {LY} N-Isopropylacrylamide {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Isopropylacrylamide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Isopropylacrylamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Isopropylacrylamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Isopropylacrylamide {} {} {} {} {} {} {} {} {} {} {}
MDL Number	MFCD00041913
PubChem Substance ID	87571754
CAS Number	2210-25-5
EC Number	218-638-5
Reaxys-RN	1744926
Beilstein Registry Number	1744926
Chemical Name Translation	N-异丙基丙烯酰胺
Wiswesser Line Notation	1Y1&MV1U1
LabNetwork Molecule ID	LN00192978
InChI	InChI=1S/C6H11NO/c1-4-6(8)7-5(2)3/h4-5H,1H2,2-3H3,(H,7,8)
Canonical SMILES	C=CC(NC(C)C)=O

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产品应用

N-异丙基丙烯酰胺是丙烯酰胺衍生物单体，由于分子内有亲水性的酰胺基和疏水性的异丙基，使其均聚物具有较低的临界溶解温度等良好特性，主要用于制造具有感温特性的聚合物凝胶，例如：药物控释材料、酶的固体材料、脱水剂、浓缩剂等。还可用于制造变性胶乳、特种涂料、胶粘剂等。
N-异丙基丙烯酰胺用于制备聚(N-异丙基丙烯酰胺)（pNIPA、pNIPAAm、p?NIPAA 或 pNIPAm）热敏性聚合物或共聚物类水凝胶。含有 NIPAM 的聚合物在高于 33°C 时急剧收缩。
该单体用于制备热敏性、遇水可膨胀的水凝胶。

安全信息

WGK Germany3

GHS Symbol

Precautionary statements

P317
P305+P354+P338
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P264+P265

Hazard statements

H302 Harmful if swallowed 吞食有害
H319 Causes serious eye irritation 严重刺激眼睛

Hazard Codes Xn

RTECSAS3675000

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Signal word Danger

Storage condition 2-8°C {LY} 2-8°C 2-8°C 储存 {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；

Risk Statements

R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1580 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - spastic paralysis with or without sensory
   change
   Lungs, Thorax, or Respiration - other changes
   Blood - hemorrhage
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0545572

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 6,51,1954

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 375 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - spastic paralysis with or without sensory
   change
   Lungs, Thorax, or Respiration - other changes
   Blood - hemorrhage
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0545572

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 419 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :

TYPE OF TEST            : Sperm Morphology
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 238 mg/kg/5W (Continuous)
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   59,201,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 2235 mg/kg
SEX/DURATION            : male 16 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   47,179,1981

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 158 gm/kg
SEX/DURATION            : male 5 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   59,201,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 238 gm/kg
SEX/DURATION            : male 5 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
   Reproductive - Fertility - male fertility index (e.g. # males impregnating
   females per # males exposed to fertile nonpregnant females)
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   59,201,1986

其他信息

Acros Organics:N-异丙基丙烯酰胺 N-Isopropylacrylamide, stabilized, pure, 99%(2210-25-5)
用途一:N-异丙基丙烯酰胺是丙烯酰胺衍生物单体，由于分子内有亲水性的酰胺基和疏水性的异丙基，使其均聚物具有较低的临界溶解温度等良好特性，主要用于制造具有感温特性的聚合物凝胶，例如：药物控释材料、酶的固体材料、脱水剂、浓缩剂等。还可用于制造变性胶乳、特种涂料、胶粘剂等。
上游原料:氢氧化钠 --> 乙酸乙酯 --> 硫酸 --> 四氢呋喃 --> 二氯甲烷 --> 乙酸 --> 石油醚 --> 硫酸钠 --> 三乙胺 --> 氯化钠 --> 异丙醇 --> 发烟硫酸 --> 丙烯腈 --> 1,4-苯二酚 --> 二异丙胺 --> 异丙胺 --> 4-甲氧基苯酚 --> 对苯二甲醚 --> 醋酸 --> 对叔丁基邻苯二酚 --> 丙烯酰氯
检测方法:HPLC,GC,NMR
MSDS 信息:N-异丙基丙烯酰胺(2210-25-5).msds
N-异丙基丙烯酰胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 TI040102 N-异丙基丙烯酰胺 25g 411元 2011/04/16 I0401 N-异丙基丙烯酰胺(含稳定剂MEHQ) N-Isopropylacrylamide (stabilized with MEHQ) 25G 411元 2011/04/16 I0401 N-异丙基丙烯酰胺(含稳定剂MEHQ) N-Isopropylacrylamide (stabilized with MEHQ) 500G 1820元
存储注意事项:热敏感
外观性质:白色结晶。
MOL 文件:2210-25-5.mol
TCI Shanghai:N-异丙基丙烯酰胺(含稳定剂甲氧基氢醌) N-Isopropylacrylamide (stabilized with MEHQ),>;98.0%(GC)(2210-25-5)
图谱信息:N-异丙基丙烯酰胺(2210-25-5)核磁图( 13 CNMR) N-异丙基丙烯酰胺(2210-25-5)红外图谱(IR2) N-异丙基丙烯酰胺(2210-25-5)红外图谱(IR1) N-异丙基丙烯酰胺(2210-25-5)核磁图( 1 HNMR) N-异丙基丙烯酰胺(2210-25-5)质谱(MS)
Sigma Aldrich:2210-25-5(sigmaaldrich)