P-Carboxybenzenesulfonyl Azide 对羧基苯磺酰叠氮化物
CAS 17202-49-2 MFCD00041753
化学结构图
SMILES: [N-]=[N+]=NS(=O)(=O)C1C=CC(=CC=1)C(O)=O
化学属性
| Mol. Formula | HO2CC6H4SO2N3 |
|---|---|
| Mol. Weight | 227.20 |
| Melting Point | 180 °C (dec.)(lit.) |
别名和识别编码
| Chemical Name | P-Carboxybenzenesulfonyl Azide |
|---|---|
| Synonym | 4-(叠氮磺酰)苯甲酸 4-羧基苯磺酰叠氮 |
| MDL Number | MFCD00041753 |
| PubChem Substance ID | 24860776 |
| CAS Number | 17202-49-2 |
| Chemical Name Translation | 对羧基苯磺酰叠氮化物 |
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分类
- {SNA} Azidation/Diazo Transfer, Azides, Building Blocks, C-X Bond Formation (Non-Halogen), Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Copper Click Chemistry, Nitrogen Compounds, Organic Azides, Organic Building Blocks, Synthetic Reagents, Various Azides
- {SNA} Azidation/Diazo Transfer, Azides, Building Blocks, C-X Bond Formation (Non-Halogen), Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Nitrogen Compounds, Organic Azides, Organic Building Blocks, Synthetic Reagents,
相关文献及参考
- A. J. P. Mortimer, et al., Org. Lett. 10 , 5477-5480, (2008)
- B. Gaspar, et al., Synthesis 24 , 3839-3845, (2007)
- F. Fringuelli, et al., Synthesis 5 , 646-650, (2000)
- FT-IR 2 (2), 3301:A / RegBook 1 (2), 2247:L / Structure Index 1 , 352:C:8
- Fieser 2 ,62 / Fieser 17 ,66
- N. Shangguan, et al., J. Am. Chem. Soc. 125 , 7754-7755, (2003)
- R. De Simone, et al., J. Med. Chem. 54 , 1565-1575, (2011)
- X. Zhang, et al., Bioconjug. Chem. 20 , 197-200, (2009)
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
