(+)-(18-Crown-6)-2,3,11,12-tetracarboxylic acid (+)-(18-冠-6)-2,3,11,12-四羧酸
CAS 61696-54-6 MFCD00040514
化学结构图
SMILES: OC(=O)[C@@H]1OCCOCCO[C@H]([C@@H](OCCOCCO[C@H]1C(O)=O)C(O)=O)C(O)=O
化学属性
| Mol. Formula | C16H24O14 |
|---|---|
| Mol. Weight | 440 |
| Melting Point | 210-212 °C (lit.) |
别名和识别编码
| Chemical Name | (+)-(18-Crown-6)-2,3,11,12-tetracarboxylic Acid |
|---|---|
| CAS Number | 61696-54-6 |
| Synonym | (+)-(18-冠-6)-2,3,11,12-四羧酸 (2R,3R,11R,12R)-1,4,7,10,13,16-Hexaoxacyclooctadecane-2,3,11,12-tetracarboxylic Acid (2R,3R,11R,12R)-1,4,7,10,13,16-六氧环十八烷-2,3,11,12-四羧酸 (+)-18-Crown-6 tetracarboxylic Acid Bis(L-tartaric Acid) 18-Crown-6 |
| MDL Number | MFCD00040514 |
| PubChem Substance ID | 24867945 |
| Beilstein Registry Number | 4240375 |
| Chemical Name Translation | (+)-(18-冠-6)-2,3,11,12-四羧酸 |
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分类
- {SNA} Chelation/Complexation Compounds, Chemical Synthesis, Crown Ethers, Synthetic Reagents
- Chelating Agents & Ligands
产品应用
- A calcium and barium chelator. A useful chiral NMR discriminating agent for underivatized amino acids.
相关文献及参考
- Behr., J-P, et al.: Helvetica Chimica Acta., 65 (6), 182, 1853 (1982),
- Dutton, P.J., et al.: Can. J. Chem., 66, 1097 (1988),
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
