CAS 75-01-4 MFCD00040415-Vinyl Chloride 乙烯基氯 TAO{mole}

Vinyl Chloride 乙烯基氯

CAS 75-01-4 MFCD00040415

化学结构图

SMILES: C=CCl

化学属性

Mol. Formula	C2H3Cl
Mol. Weight	62.50
Refractive index	n20/D 1.3700(lit.)
Boiling Point	-13.4 °C(lit.)
Density	0.7915
Melting Point	-153.8 °C(lit.)
Flash Point	-78 °F
Solubility	acetone/carbon disulfide, MEK, THF: soluble
Appearance	powder

别名和识别编码

Chemical Name	Vinyl Chloride
Synonym	{uni_hamburg} 氯乙烯 chloro-ethene monomeres Vinylchorid vinylchloride CHLOROETHYLENE 1-Chloroethene chloro-Ethene chloro-ethylen Vinyl C monomer Monochloräthylen C₂H₃Cl (chloro-ethene) chloroacetylene Chlorethylen Vinyl chloride monomer Chlorethylene 乙烯基氯 Monochloroethylene 1-Chlor-αthen Vinile (cloruro di) 1-Chlorethen VCM Ethylene monochloride chloroethene Winylu chlorek F 1140 Cloruro di vinile Monochloroethene Chlorethen Chloroethylene C2H3Cl RCRA waste number U043 Ethylene, chloro- Vinylchlorid Chloroethene Vinyl chloride 1-Chlor-äthen vinyl chloride Ethene, chloro- 氯乙炔 chloroethyne VINYL CHLORIDE Vinyle(chlorure de) chloruredevinyle Chlorure de vinyle Chloroacetylenecation Chlorethene chloro-ethen 1-Chloroethylene
MDL Number	MFCD00040415
CAS Number	75-01-4
PubChem Substance ID	6338
EC Number	200-659-6
Beilstein Registry Number	1731576
Chemical Name Translation	乙烯基氯
Merck Number	13,10055
Wiswesser Line Notation	G1U1
InChI	InChI=1S/C2H3Cl/c1-2-3/h2H,1H2

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

GHS Symbol

WGK Germany2

Hazard statements

H220 Extremely flammable gas 极易燃气体。
H350 May cause cancer 可能致癌
H280 Contains gas under pressure; may explode if heated 内含高压气体，遇热可能爆炸。

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US) Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)

RTECSKU9625000

Precautionary statements

P410+P403
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P308+P313
P201 Obtain special instructions before use. 使用前获取专门指示。

Signal word Danger

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Hazard Codes F+,T F+,T,F

Risk Statements

R45 May cause cancer 可能致癌
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R11 Highly flammable 非常易燃
R12 Extremely flammable 极端易燃
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险

Hazard Class2.1

Storage condition 储存温度2-8℃ 2-8°C

UN Number UN 1086 2.1

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10000 ppm/4H
                          female 12-18 day(s) after conception
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Reproductive - Tumorigenic effects - transplacental tumorigenesis
   Endocrine - tumors
REFERENCE :
   CSHCAL Cold Spring Harbor Conferences on Cell Proliferation.  (Cold Spring
   Harb

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 21 mg/kg/65W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Skin and Appendages - tumors
   Gastrointestinal - tumors
REFERENCE :
   APDCDT Advances in Tumour Prevention, Detection and Characterization.  (New
   York, NY)  V.1-5, 1974-80.  Discontinued.  Volume(issue)/page/year:
   3,216,1976

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3463 mg/kg/52W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Kidney, Ureter, Bladder - Kidney tumors
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 41,3,1981

TYPE OF TEST            : TC - Toxic concentration (other than lowest)
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 300 mg/m3/W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Blood - tumors
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 11309

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 200 ppm/18M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IPSTB3 International Polymer Science and Technology.  (Rapra Technology
   Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year:
   3,93,1976

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : I

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 18 pph/15M
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   HUTODJ Human Toxicology.  (Macmillan Press Ltd., Houndmills, Basingstoke,
   Hants., RG 21 2XS, UK) V.1-    1981-  Volume(issue)/page/year: 1,239,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DOWCC* Dow Chemical Company Reports.  (Dow Chemical USA, Health and
   Environment Research, Toxicology Research Lab., Midland, MI 4

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 30 pph/30M
TOXIC EFFECTS :
   Behavioral - general anesthetic
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   21,394,1960

{h

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 10600 umol/L
REFERENCE :
   BCPCA6 Biochemical Pharmacology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.1-    1958-  Volume(issue)/page/year:
   24,2013,1975

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 48 mmol/L/3H
REFERENCE :
   MUREAV Mutat

TYPE OF TEST            : Sex chro

TYPE OF TEST            : DNA inhibition
ROUTE OF EXPOSURE       : Intravenous
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 9500 ug/kg
REFERENCE :
   CBINA8 Chemico-Biological Interactions.  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1969-  Volume(issue)/page/year:
   17,239,1977

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 10 pph
REFERENCE :
   EVSRBT Environmental Science Research.  (Plenum Pub. Corp., 233 Spring St.,
   New York, NY 10013) V.1-    1972-  Volume(issue)/page/year: 25,91,1982

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Schizosaccharomyces pombe
DOSE/DURATION           : 16 mmol/L/30M
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 40,85,1976

TYPE OF TEST

TYPE OF

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Multiple routes
TEST SYSTEM             : Rodent - hamster
DOSE/DURATION           : 600 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    19

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 500 ppm/7H
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 41,171,1981

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1500 ppm/24H
SEX/DURATION            : female 1-9 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 11,45,1978

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE                    : 500 ppm/7H
SEX/DURATION            : female 6-18 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 41,171,1981

Warnings 危险化学品

其他信息

下游产品:异丙氧基乙醇
爆炸物危险特性:与空气混合明火、受热可爆
方法一:1.乙烯氧氯化法该法是世界公认为技术经济较合理的方法。乙烯与氯气在三氯化铁催化剂存在下，液相直接氯化生成1,2-二氯乙烷。1,2-二氯乙烷经精制后裂解，得氯乙烯和氯化氢，经精馏得到成品氯乙烯。副产氯化氢、乙烯与空气，通过载于氧化铝上的氯化铜触媒进行氧氯化反应得1,2-二氯乙烷，精制后在500℃、2.0-2.5MPa压力下，在管式炉内裂解生成氯乙烯和氯化氢，精制得产品氯乙烯。副产品氯化氢可再返回氧氯化反应器与乙烯再进行氧氯化反应。2.乙炔气相合成法本法工艺简单，产品纯度高，但耗电量大，成本高，并有汞污染问题。由电石发生的乙炔与氯化氢混合，在氯化汞存在下，于170-190℃进行反应，反应产物经水洗、碱洗、压缩、全凝、初馏、精馏，得氯乙烯单体。3.乙烯直接氯化法4.烯炔联合法
上游原料:酸性氧化铝 --> 三氯化铁 --> 1,2-二氯乙烷 --> 碳化钙 --> 乙炔 --> 氯化汞 --> 氯乙烯单体
防护措施:对人体有麻醉作用。含量达20%～40%时，可使人发生急性中毒而失去知觉，呼吸渐缓，终致死亡。长期接触能引起指骨溶失症或肝脾肿大等症状。也有报道，氯乙烯会致癌，但有一定争论。发现急性中毒时应及早移出现场，静卧保暖、松衣、输氧气或人工呼吸。如皮肤被液体污染，宜用大量清水冲洗。生产设备应严防跑、冒、滴、漏。操作人员应配戴防护用具。空气中最高容许浓度1ppm。
类别:有害气体
储运特性:库房通风低温干燥; 轻装轻卸; 与氧气、空气等助燃气体钢瓶分开存放
Sigma Aldrich:75-01-4(sigmaaldrich)
毒性分级:中毒
职业标准:TWA 10 毫克/ 立方米; STEL 30 毫克/ 立方米
F:4.5-31
外观性质:无色、有醚样气味的气体。
MSDS 信息:氯乙烯(75-01-4).msds
可燃性危险特性:明火、受热可燃; 燃烧产生有毒氯化物烟雾
灭火剂:雾状水、二氧化碳、泡沫
急性毒性:吸入- 大鼠 LC50: 18000 PPM/ 15分; 口服- 大鼠 LD50: 500 毫克/ 公斤
MOL 文件:75-01-4.mol
常规方法:可用管道、耐压贮罐贮运。应隔绝明火，避免和氧化剂接近，防止日晒、受热，运输中防止撞击。公路、铁路均可运输。
用途一:用作多种聚合物的共聚单体
用途二:塑料工业的重要原料，主要用于生产聚氯乙烯树脂。与醋酸乙烯、偏氯乙烯、丁二烯、丙烯腈、丙烯酸酯类及其他单体共聚生成共聚物，也可用作冷冻剂等。