Boron trifluoride tetrahydrofuran 三氟化硼-四氢呋喃
CAS 462-34-0 MFCD00040372
化学结构图
SMILES: F[B-](F)(F)[O+]1CCCC1
化学属性
| Mol. Formula | C4H8BF3O |
|---|---|
| Mol. Weight | 139.91 |
| Density | 1.268 |
| Flash Point | 92°(197°F) |
| TSCA | Yes |
| Boiling Point | 180 °C at 760 mmHg |
| Melting Point | 11-13 °C |
| Solubility | 水解 |
| Stability | 对光敏感 |
别名和识别编码
| Chemical Name | Boron trifluoride tetrahydrofuran |
|---|---|
| Synonym | Boron trifluoride tetrahydrofuran complex {LY} Boron trifluoride tetrahydrofuran complex {} {LY} Boron trifluoride tetrahydrofuran complex {} {} {LY} Boron trifluoride tetrahydrofuran complex {} {} {} {LY} Boron trifluoride tetrahydrofuran complex {} {} {} {} {LY} Boron trifluoride tetrahydrofuran complex {} {} {} {} {} {LY} Boron trifluoride tetrahydrofuran complex {} {} {} {} {} {} {LY} Boron trifluoride tetrahydrofuran complex {} {} {} {} {} {} {} {LY} Boron trifluoride tetrahydrofuran complex {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Boron trifluoride tetrahydrofuran complex {} {} {} {} {} {} {} {} {} {LY} Boron trifluoride tetrahydrofuran complex {} {} {} {} {} {} {} {} {} {} {LY} Boron trifluoride tetrahydrofuran complex {} {} {} {} {} {} {} {} {} {} {} {LY} Boron trifluoride tetrahydrofuran complex {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Boron trifluoride tetrahydrofuran complex {} {} {} {} {} {} {} {} {} {} |
| MDL Number | MFCD00040372 |
| CAS Number | 462-34-0 |
| EC Number | 207-325-9 |
| PubChem Substance ID | 60146129 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | 三氟化硼-四氢呋喃 |
| InChIKey | CHNLPLHJUPMEOI-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN02139154 |
| InChI | InChI=1S/C4H8BF3O/c6-5(7,8)9-3-1-2-4-9/h1-4H2 |
| Canonical SMILES | F[B-]([O+]1CCCC1)(F)F |
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分类
- {SNA} Acids, Acids & Bases, Boron, Boron Catalysts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Lewis Acids, Synthetic Reagents
- {uni_hamburg} no charge; oxygen heterocycle; alicycle; 5ring; 1fragment
- {SNA} Acids, Acids & Bases, Boron, Catalysis and Inorganic Chemistry, Chemical Synthesis, Lewis Acids, Synthetic Reagents
- {SNA} Boron, Catalysis and Inorganic Chemistry, Chemical Synthesis, Lewis Acids, Synthetic Reagents
产品应用
- 用作有机反应的催化剂、聚合反应的抑制剂以及作为医药中间体。
相关文献及参考
- Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
- R34 Causes burns 会导致灼伤
- R35 Causes severe burns 会导致严重灼伤
- R48/23
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
其他信息
- Acros Organics:三氟化硼四氢呋喃溶液 Boron trifluoride tetrahydrofuran complex, 50%(462-34-0)
- Hazard Note:Toxic/Corrosive
- Sigma Aldrich:462-34-0(sigmaaldrich)
- 用途一:用作有机反应的催化剂、聚合反应的抑制剂以及作为医药中间体。
- MOL 文件:462-34-0.mol
- 水中分解。
- Alfa Aesar:三氟化硼四氢呋喃络合物,95% Boron trifluoride-tetrahydrofuran complex, 95%(462-34-0)
- 三氟化硼四氢呋喃络合物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 388635000 三氟化硼四氢呋喃络合物 Boron trifluoride tetrahydrofuran complex 50% 500 ML 880元 2010/06/21 388631000 三氟化硼四氢呋喃络合物 Boron trifluoride tetrahydrofuran complex 50% 100 ML 370元 2010/05/25 L17593 三氟化硼四氢呋喃络合物,95% Boron trifluoride-tetrahydrofuran complex, 95% 500g 560元
- 敏感性:Moisture Sensitive
- MSDS 信息:Boron trifluoride tetrahydrofuran complex(462-34-0).msds
