2,2-Dichloro-1,1-Difluoroethyl Methyl Ether 2,2-二氯-1,1-二氟乙基 甲基 醚
CAS 76-38-0 MFCD00040144
化学结构图
SMILES: COC(F)(F)C(Cl)Cl
化学属性
| Mol. Formula | C3H4Cl2F2O |
|---|---|
| Mol. Weight | 165 |
| Boiling Point | 103-104.5° |
| Melting Point | -35° |
| Density | 1.440 |
| Flash Point | 37°(98°F) |
| TSCA | No |
| Appearance | 无色易流动的透明液体。熔点-35℃，沸点105℃，（13.3kPa），相对密度（20/4℃）1.4262，折光率（nD20）1.3861。有水果香味。 |
| Refractive index | 1.386 |
别名和识别编码
| Chemical Name | 2,2-Dichloro-1,1-Difluoroethyl Methyl Ether |
|---|---|
| CAS Number | 76-38-0 |
| Alfabeta Name | DICHLORODIFLUOROETHYLMETHYLETHER 2211()---,, |
| MDL Number | MFCD00040144 |
| Synonym | 2-methoxyethane, 1,1-dichloro-2,2-difluoro- methoxyflurane (INN) Methoflurane 2-methoxyethane,1,1-dichloro-2,2-difluoro- {uni_hamburg} 2,2-二氯-1,1-二氟-1-甲氧乙烷 2,2-dichloro-1,1-difluoro-1-methoxyethane Anecotan Pentrane Methoxyfluoran ether,2,2-dichloro-1,1-difluoroethylmethyl DA-759 2,2-Dichloro-1,1-difluoro-1-methoxyethane 2,2-二氯-1,1-二氟乙基 甲基 醚, 97% Ether, 2,2-dichloro-1,1-difluoroethyl methyl 甲氧氟乙烷 Methoxiflurane Methyl 1,1-difluoro-2,2-dichloroethyl ether Analgizer Pentran Methofane Ingalan Metoxifluran 2,2-DICHLORO-1,1-DIFLUOROETHYL METHYL ETHER METHOXYFLURANE 2,2-二氯-1,1-二氟乙基甲基醚 Methoxane Metofane METOFANE Penthrane 甲氧氟烷 Inhalan 2,2-dichloro-1,1-difluoro-1-methoxy-ethan Methoxyfluran Metoxfluran 1,1-Dichloro-2,2-difluoro-2-methoxy ethane NSC-110432 二氟二氯乙基甲醚 Methoxyflurane 1,1-dichloro-2,2-difluoro-2-methoxyethane Ethane, 2,2-dichloro-1,1-difluoro-1-methoxy- 2,2-Dichloro-1,1-difluoroethyl methyl ether |
| EC Number | 200-956-0 |
| Merck Number | 14,5994 |
| Beilstein Registry Number | 1737766 |
| Chemical Name Translation | 2,2-二氯-1,1-二氟乙基 甲基 醚 |
| Wiswesser Line Notation | GYGXFFO1 |
| LabNetwork Molecule ID | LN00119616 |
| PubChem Substance ID | 4116 |
| InChI | InChI=1S/C3H4Cl2F2O/c1-8-3(6,7)2(4)5/h2H,1H3 |
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相关文献及参考
- Short: II/19b Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19b Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54578-6 ISBN: 978-3-540-54578-1 Internet Resource: DOI:10.1007/b44334 RefComment: XI, 488 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new objects of interest such as molecular complexes and clusters accessible to study. Subvolume II/19b contains corresponding data on diamagnetic asymmetric top molecules.
- Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- R10 Flammable 易燃
- R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
- R36 Irritating to eyes 刺激眼睛
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Mammal - species unspecified DOSE/DURATION : 3600 mg/kg TOXIC EFFECTS : Behavioral - antipsychotic REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 24(4),55,1980
TYPE OF TES
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 33500 mg/m3/4H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., e
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 150 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : USXXAM United States Patent Document. (U.S. Patent Office, Box 9, Washington, DC 20231) Volume(issue)/page/year: #4168308
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 21500 mg/m3 TOXIC EFFECTS : Behavioral - general anesthetic Behavioral - somnolence (general depressed activity) Behavioral - excitement REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 22(7),55,1978
TYPE OF TEST : Mutation test systems - not otherwise specified TEST SYSTEM : Rodent - hamster Fibroblast DOSE/DURATION : 1 pph REFERENCE : ANESAV Anesthesiology. (Lippincott/Harper, Journal Fulfillment Dept., 2350 Virginia Ave., Hagerstown, MD 21740) V.1- 1940- Volume(issue)/page/year: 43,21,1975
TYPE OF TEST : Mutation test systems - not otherwise specified ROUTE OF EXPOSURE : Inhalation TEST SYSTEM : Rodent - rat DOSE/DURATION : 5000 ppm/3H (Continuous) REFERENCE : EXPEAM Experientia. (Birkhaeuser Verlag, POB 133, CH-4010 Basel, Switzerland) V.1- 1945- Volume(issue)/page/year: 35,71,1979
TYPE OF TEST : Cytogenetic analysis ROUTE OF EXPOSURE : Parenteral TEST SYSTEM : Bird - chicken DOSE/DURATION : 10 mg REFERENCE : ENVRAL Environmental Research. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1967- Volume(issue)/page/year: 12,366,1976
TYPE OF TEST : Cytogenetic analysis TEST SYSTEM : Human Lymphocyte DOSE/DURATION : 200 ppm/24H REFERENCE : ENVRAL Environmental Research. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1967- Volume(issue)/page/year: 12,366,1976
TYPE OF TEST : Cytogenetic analysis TEST SYSTEM : Rodent - mouse Fibroblast DOSE/DURATION : 100 ppm REFERENCE : ENVRAL Environmental Research. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1967- Volume(issue)/page/year: 12,366,1976
TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE : 2 ppm/4H SEX/DURATION
TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE : 400 ppm/8H SEX/DURATION : female 1-21 day(s) after conception TOXIC EFFECTS : Reproductive - Specific Developmental Abnormalities - musculoskeletal system REFERENCE : ANESAV Anesthesiology. (Lippincott/Harper, Journal Fulfillment Dept., 2350 Virginia Ave., Hagerstown, MD 21740) V.1- 1940- Volume(issue)/page/year: 48,11,1978
TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE : 2000 ppm/4H SEX/DURATION : female 6-15 day(s) after conception TOXIC EFFECTS : Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Specific Developmental Abnormalities - musculoskeletal system REFERENCE : AACRAT Anesthesia and Analgesia (New York). (Elsevier Science Pub. Co., Inc., 52 Vanderbilt Ave., New York, NY 10017) V.36- 1957- Volume(issue)/page/year: 59,421,1980
TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE : 100 ppm/8H SEX/DURATION : female 1-21 day(s) after conception TOXIC EFFECTS : Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) REFERENCE : ANESAV Anesthesiology. (Lippincott/Harper, Journal Fulfillment Dept., 2350 Virginia Ave., Hagerstown, MD 21740) V.1- 1940- Volume(issue)/page/year: 48,11,1978
{haz其他信息
- 用途一:为较新的全身吸入麻醉剂。在已知的吸入全麻药中，其全麻效能最强，并有明显的肌松作用。现多用于浅全麻。
- Sigma Aldrich:76-38-0(sigmaaldrich)
- MOL 文件:76-38-0.mol
- Alfa Aesar:2,2-二氯-1,1-二氟乙基甲基醚,97% 2,2-Dichloro-1,1-difluoroethyl methyl ether, 97%(76-38-0)
- Hazard Note:Irritant
- 方法一:将1，2，-二氟-1，1，2，2-四氯乙烷重排成1，1-二氟-1，2，2，2-四氯乙烷，再脱去1分子CL2，然后与甲醇加成，即得甲氧氟烷。
- 上游原料:氘代四氯乙烷
