4-Fluorobenzeneboronic acid 4-氟苯硼酸
CAS 1765-93-1 MFCD00039136
化学结构图
SMILES: OB(O)c1ccc(F)cc1
化学属性
| Mol. Formula | C6H6BFO2 |
|---|---|
| Mol. Weight | 139.92 |
| Melting Point | 262-265 |
| TSCA | No |
| Density | 1.24 |
| Appearance | white to off-white pwdr. |
| Boiling Point | 258.4±42.0 °C at 760 mmHg |
别名和识别编码
| Chemical Name | 4-Fluorobenzeneboronic acid |
|---|---|
| CAS Number | 1765-93-1 |
| Alfabeta Name | FLUOROPHENYLBORONICACID 4- |
| MDL Number | MFCD00039136 |
| Synonym | 4-Fluorobenzeneboronic acid {LY} 4-Fluorobenzeneboronic acid {} {LY} 4-Fluorobenzeneboronic acid {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorobenzeneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorob |
| Beilstein Registry Number | 2829653 |
| PubChem Substance ID | 285645 |
| Reaxys-RN | 2829653 |
| EC Number | 250-023-7 |
| Chemical Name Translation | 4-氟苯硼酸 |
| LabNetwork Molecule ID | LN00008272 |
| InChI | InChI=1S/C6H6BFO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H |
| Canonical SMILES | FC1=CC=C(B(O)O)C=C1 |
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分类
- {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
- Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
产品应用
- 用于四溴噻吩的Suzuki偶联反应中，也用于钯催化加腈。广泛用在和芳烃四氟硼酸重氮盐、碘盐的偶联反应，以及制造活性三联苯。
相关文献及参考
- 8. Zhang, J.; et al. , Ligand-free copper-catalyzed coupling of nitroarenes with arylboronic acids Green Chem. 4th ed., 14 , 912-916, (2012)
- 5. Inamoto, K.; et al. , Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: a novel route to 4-aryl-2-quinolinones Chem. Commun. 36th ed., 48 , 4332-4334, (2012) 摘要
- 7. Xue, F.; et al. , Rhodium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Nitroalkenes Using Olefin-Sulfoxide Ligands J. Org. Chem. 7th ed., 77 , 3071-3081, (2012) 摘要
- 6. Dastbaravardeh, N.; Schnuerch, M.; Mihovilovic, M. D. , Ruthenium(0)-Catalyzed sp3 C-H Bond Arylation of Benzylic Amines Using Arylboronates Org. Lett. 7th ed., 14 , 1930-1933, (2012) 摘要
- Beilstein: 16,IV,1666
- For reactions of boronic acids, see Appendix 5.
- GC reagent for diols: J. Chromat., 158, 33 (1978); 186, 307 (1979).
安全信息
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P305+P351+P338+P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H302 Harmful if swallowed 吞食有害
- H319 Causes serious eye irritation 严重刺激眼睛
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- 用途二:用于四溴噻吩的Suzuki偶联反应中，也用于钯催化加腈。广泛用在和芳烃四氟硼酸重氮盐、碘盐的偶联反应，以及制造活性三联苯。
- Alfa Aesar:4-氟苯硼酸,97% 4-Fluorobenzeneboronic acid, 97%(1765-93-1)
- 下游产品:6-(4-氟苯基)吡啶-2-醛
- Hazard Note:Irritant
- Acros Organics:4-氟苯硼酸 4-Fluorophenylboronic acid, 97%(1765-93-1)
- 用途一:Suzuki偶联反应中的常用有机合成试剂
- F:10-21
- 4-氟苯硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw070019 4-氟苯硼酸 10g 400元 2011/04/16 F0361 4-氟苯硼酸(含有数量不等的酸酐) 4-Fluorophenylboronic Acid (contains varying amounts of Anhydride) 25G 1550元 2011/04/16 F0361 4-氟苯硼酸(含有数量不等的酸酐) 4-Fluorophenylboronic Acid (contains varying amounts of Anhydride) 5G 580元
- Sigma Aldrich:1765-93-1(sigmaaldrich)
- MOL 文件:1765-93-1.mol
- TCI Shanghai:4-氟苯硼酸(含有数量不等的酸酐) 4-Fluorophenylboronic Acid (contains varying amounts of Anhydride)(1765-93-1)
