CAS 3886-08-6 MFCD00038274-Z-Glu(OtBu)-OH N-苄氧羰基-L-谷氨酸 γ-叔丁酯 TAO{mole}

Z-Glu(OtBu)-OH N-苄氧羰基-L-谷氨酸 γ-叔丁酯

CAS 3886-08-6 MFCD00038274

化学结构图

SMILES: CC(C)(C)OC(=O)CC[C@H](NC(=O)OCc1ccccc1)C(=O)O

化学属性

Mol. Formula	C17H23NO6
Mol. Weight	337.37
Melting Point	83-87°C
TSCA	No
Density	1.197
Appearance	白色结晶或结晶性粉末，溶于甲醇和乙醇，不溶于石油醚；mp为85-87℃；比旋光度[α] -9.5°(0.5-2 mg/ml，乙醇)。 D -15°-17°(0.5-2mg/ml，甲醇)， [α] 20
Boiling Point	522.6°C at 760 mmHg

别名和识别编码

Chemical Name	Z-Glu(OtBu)-OH
MDL Number	MFCD00038274
Synonym	Z-Glu(OtBu)-OH {LY} Z-Glu(OtBu)-OH {} {LY} Z-Glu(OtBu)-OH {} {} {LY} Z-Glu(OtBu)-OH {} {} {} {LY} Z-Glu(OtBu)-OH {} {} {} {} {LY} Z-Glu(OtBu)-OH {} {} {} {} {} {LY} Z-Glu(OtBu)-OH {} {} {} {} {} {} {LY} Z-Glu(OtBu)-OH {} {} {} {} {} {} {} {LY} Z-Glu(OtBu)-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Glu(OtBu)-OH {} {} {} {} {} {} {} {} {} {LY} Z-Glu(OtBu)-OH {} {} {} {} {} {} {} {} {} {} {LY} Z-Glu(OtBu)-OH {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Glu(OtBu)-OH {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Glu(OtBu)-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Glu(OtBu)-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Glu(OtBu)-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Glu(OtBu)-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Z-Glu(OtBu)-OH {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number	223-421-3
CAS Number	3886-08-6
PubChem Substance ID	107472
Beilstein Registry Number	2570100
Reaxys-RN	2570100
Chemical Name Translation	N-苄氧羰基-L-谷氨酸 γ-叔丁酯
InChIKey	GLMODRZPPBZPPB-ZDUSSCGKSA-N
LabNetwork Molecule ID	LN01366347
InChI	InChI=1S/C17H23NO6/c1-17(2,3)24-14(19)10-9-13(15(20)21)18-16(22)23-11-12-7-5-4-6-8-12/h4-8,13H,9-11H2,1-3H3,(H,18,22)(H,20,21)/t13-/m0/s1
Canonical SMILES	O=C([C@H](CCC(OC(C)(C)C)=O)NC(OCC1=CC=CC=C1)=O)O

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

WGK Germany3

GHS Symbol

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352
P304+P340
P305+P351+P338
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P332+P317
P333+P313
P333+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Signal word Warning

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S37 Wear suitable gloves 戴适当手套；

Hazard Codes Xi

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应

Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

方法一:以叔丁醇和苄氧羰基-L-谷氨酸为原料，进行酯化反应，经结晶纯化后得产品。
Alfa Aesar:N-苄氧羰基-L-谷氨酸γ-叔丁酯,97% N-Benzyloxycarbonyl-L-glutamic acid gamma-tert-butyl ester, 97%(3886-08-6)
比旋光度:-14 ° (c=2% in MeOH)
N-苄氧羰基-L-谷氨酸 5-叔丁酯价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 C1715 N-苄氧羰基-L-谷氨酸5-叔丁酯 5-tert-Butyl N-Carbobenzoxy-L-glutamate 5G 576元 2010/05/25 B22557 N-苄氧羰基-L-谷氨酸γ-叔丁酯, 97% N-Benzyloxycarbonyl-L-glutamic acid gamma-tert-butyl ester, 97% 5g 1820元 2010/05/25 B22557 N-苄氧羰基-L-谷氨酸γ-叔丁酯, 97% N-Benzyloxycarbonyl-L-glutamic acid gamma-tert-butyl ester, 97% 1g 575元
参考质量标准:mp为80-86℃；比旋光度[α] 20 D -8.8°-10.8°(0.5-2mg/ml，乙醇)；乙醇溶解试验和层析试验合格。
TCI Shanghai:N-苄氧羰基-L-谷氨酸5-叔丁酯 N-Carbobenzoxy-L-glutamic Acid 5-tert-Butyl Ester,>;98.0%(LC)(T)(3886-08-6)
MOL 文件:3886-08-6.mol
上游原料:叔丁醇 --> N-苄氧羰基-L-谷氨酸
Sigma Aldrich:3886-08-6(sigmaaldrich)
用途一:用作氨基酸保护单体，用于多肽合成。