(2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide (乙氧基羰基甲基)二甲基溴化硫鎓
CAS 5187-82-6 MFCD00031604
化学结构图
SMILES: CCOC(=O)C[S+](C)C.[Br-]
化学属性
| Mol. Formula | C6H13BrO2S |
|---|---|
| Melting Point | 90-94 °C |
| TSCA | No |
| Mol. Weight | 229.14 |
别名和识别编码
| MDL Number | MFCD00830557 |
|---|---|
| Synonym | (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)dimethylsulfo |
| EC Number | 225-968-3 |
| CAS Number | 5187-82-6 |
| Beilstein Registry Number | 4161472 |
| InChIKey | JXFPTJYKYKVENJ-UHFFFAOYSA-M |
| Chemical Name | (2-Ethoxy-2-oxoethyl)dimethylsulfonium bromide |
| Chemical Name Translation | (乙氧基羰基甲基)二甲基溴化硫鎓 |
| PubChem Substance ID | 78861 |
| InChI | InChI=1S/C6H13O2S.BrH/c1-4-8-6(7)5-9(2)3;/h4-5H2,1-3H3;1H/q+1;/p-1 |
| Canonical SMILES | C[S+](CC(OCC)=O)C.[Br-] |
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相关文献及参考
- The derived ylide does not add to carbonyl compounds, although it does undergo 1,4-addition to enones, with formation of cyclopropanecarboxylic esters: Tetrahedron, 23, 545, (1967); J. Org. Chem., 34, 1240 (1969).
- Review of the chemistry of sulfonium ylides: Russ. Chem. Rev., 50, 481 (1981).
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
