(4-Methoxybenzyl)triphenylphosphonium chloride (4-甲氧基苄基)三苯基氯化膦
CAS 3462-97-3 MFCD00031572
化学结构图
SMILES: [Cl-].COC1C=CC(C[P+](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1
化学属性
| Mol. Formula | C26H24ClOP |
|---|---|
| Mol. Weight | 418.90 |
| Melting Point | 236-238 °C |
| TSCA | No |
别名和识别编码
| Chemical Name | (4-Methoxybenzyl)triphenylphosphonium chloride |
|---|---|
| MDL Number | MFCD00031572 |
| CAS Number | 3462-97-3 |
| Beilstein Registry Number | 4173378 |
| Chemical Name Translation | (4-甲氧基苄基)三苯基氯化膦 |
| Synonym | (4-Methoxybenzyl)triphenylphosphonium chloride {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} (4-Methoxybenzyl)triphenylphosphonium ch |
| LabNetwork Molecule ID | LN01305631 |
| Canonical SMILES | COC1=CC=C(C[P+](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4)C=C1.[Cl-] |
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相关文献及参考
- Benzylic phosphonium salts undergo the Wittig reaction with aromatic aldehydes using solid KOH in the presence of 18-crown-6 to give (Z)-stilbenes with good stereoselectivity: Tetrahedron Lett., 37, 4225 (1996). See Appendix 1.
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- MOL 文件:3462-97-3.mol
- Acros Organics:(4-甲氧基苄基)三苯基氯化膦 (4-Methoxybenzyl)triphenylphosphoniumchloride,98%(3462-97-3)
- (4-甲氧基苄基)三苯基氯化膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 376320250 (4-甲氧基苄基)三苯基氯化膦 (4-Methoxybenzyl)triphenylphosphonium chloride 98% 25 GR 2103元 2010/06/21 376321000 (4-甲氧基苄基)三苯基氯化膦 (4-Methoxybenzyl)triphenylphosphonium chloride 98% 100 GR 5932元 2010/06/21 376320050 (4-甲氧基苄基)三苯基氯化膦 (4-Methoxybenzyl)triphenylphosphonium chloride 98% 5 GR 654元
- Sigma Aldrich:3462-97-3(sigmaaldrich)
- Alfa Aesar:（4－甲氧基苄基）三苯基氯化膦,97% (4-Methoxybenzyl)triphenylphosphonium chloride, 97%(3462-97-3)
