CAS 5332-25-2 MFCD00024023-6-Bromoquinoline 6-溴喹啉 TAO{mole}

6-Bromoquinoline 6-溴喹啉

CAS 5332-25-2 MFCD00024023

化学结构图

SMILES: Brc1ccc2ncccc2c1

化学属性

Mol. Formula	C9H6BrN
Mol. Weight	208.06
Density	1.538
Refractive index	1.6600 to 1.6650
Flash Point	>110°C
TSCA	Yes
Melting Point	19°C
Stability	对光敏感
Boiling Point	278°C at 760 mmHg
pH	:A

别名和识别编码

Chemical Name	6-Bromoquinoline
CAS Number	5332-25-2
Alfabeta Name	BROMOQUINOLINE 6-
MDL Number	MFCD00024023
Synonym	6-Bromoquinoline {LY} 6-Bromoquinoline {} {LY} 6-Bromoquinoline {} {} {LY} 6-Bromoquinoline {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number	226-238-7
Reaxys-RN	112964
Beilstein Registry Number	20(5)7,319
PubChem Substance ID	79243
Chemical Name Translation	6-溴喹啉
InChIKey	IFIHYLCUKYCKRH-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00120989
InChI	InChI=1S/C9H6BrN/c10-8-3-4-9-7(6-8)2-1-5-11-9/h1-6H
Canonical SMILES	C1=CC=C2C(=N1)C=CC(=C2)Br

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

Warnings IRRITANT

WGK Germany3

GHS Symbol

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312
P302+P350
P302+P352
P302+P352+P332+P313+P362+P364
P304+P340
P305+P351+P338
P305+P351+P338+P337+P313
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Hazard statements

H302 Harmful if swallowed 吞食有害
H315 Causes skin irritation 会刺激皮肤
H318 Causes serious eye damage 严重伤害眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Storage condition 2-8°C {LY} 2-8°C 2-8℃避光储存 Refrigerator Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Risk Statements

R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
S39 Wear eye/face protection 戴眼睛/面孔保护装置；

Hazard Codes Xi,Xn Xn Xi

其他信息

用途和制备方法:3-溴喹啉与混酸作用生成3-溴-5-硝基喹啉，与高锰酸钾加热被氧化为5-溴-2，3-吡啶二甲酸。 6-溴喹啉与硝酸加热生成6-溴-8-硝基喹啉，与高锰酸钾作用被氧化为2，3- 吡啶二甲酸。由2-羟基喹啉与五溴化磷作用制得2-溴喹啉。由喹啉过溴化物于180℃加热制得3-溴喹啉。由4-羟基喹啉与五溴化磷加热，或由4-氨基喹啉经重氮化反应制得4-溴喹啉。 5-溴喹啉由间溴苯胺、甘油、间溴硝基苯及浓硫酸加热，或由5-氨基喹啉经重氮化反应制取。由对溴苯胺与甘油、浓硫酸、对溴硝基苯加热制得6-溴喹啉。由7-氨基喹啉经重氮化反应制得7-溴喹啉。 8-溴喹啉由邻溴苯胺、甘油、浓硫酸及邻溴硝基苯加热制得。用途：作有机合成试剂。
6-溴喹啉价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 B2015 6-溴喹啉 6-Bromoquinoline 5G 1280元 2014/06/02 B2015 6-溴喹啉 6-Bromoquinoline 1G 429元 2010/06/21 CC04510CB 6-溴喹啉 6-bromoquinoline 250 MG 900元
Acros Organics:6-溴喹啉 6-bromoquinoline(5332-25-2)
图谱信息:6-溴喹啉(5332-25-2)质谱(MS) 6-溴喹啉(5332-25-2)红外图谱(IR1) 6-溴喹啉(5332-25-2)核磁图( 13 CNMR) 6-溴喹啉(5332-25-2)核磁图( 1 HNMR)
TCI Shanghai:6-溴喹啉 6-Bromoquinoline,>;95.0%(GC)(5332-25-2)
检测方法:HPLC
存储注意事项:氮气保护
MOL 文件:5332-25-2.mol
Hazard Note:Irritant
Sigma Aldrich:5332-25-2(sigmaaldrich)
上游原料:氢氧化钠 --> 硫酸 --> 四氢呋喃 --> 甲苯 --> 正丁醇 --> 氯化锌 --> 甘油 --> 丙烯醛 --> 4-溴苯胺 --> 四氯苯醌 --> 1-溴-4-硝基苯
溴喹啉:有七种位置异构体，其主要物性列表如下：名称熔点(℃) 沸点(℃) 溶解性 2-溴喹啉 48～49 溶于乙醚、氯仿、苯 3-溴喹啉 12～15 274～276、 95(66.66Pa) 4-溴喹啉 29～30 270(分解) 易溶于稀酸 5-溴喹啉 52(针状晶体) 280 　 6-溴喹啉 24 278 7-溴喹啉 52(针状晶体) 290 8-溴喹啉 80 165～166 (2399.79Pa)