CAS 1192-30-9 MFCD00016894-Tetrahydrofurfuryl bromide 四氢呋喃甲基溴 TAO{mole}

Tetrahydrofurfuryl bromide 四氢呋喃甲基溴

CAS 1192-30-9 MFCD00016894

化学结构图

SMILES: BrCC1CCCO1

化学属性

Mol. Formula	C5H9BrO
Mol. Weight	165.03
Refractive index	1.4850 to 1.4890
Density	1.452
Flash Point	73°C(lit.)
TSCA	Yes
Boiling Point	181.4°C at 760 mmHg
Appearance	液体。沸点168-170℃（98.95kPa），69-70℃（2.93kPa），60-61℃（1.6kPa），相对密度1.3653（20/4℃），折光率1.4850。溶于乙醚和乙醇。

别名和识别编码

Chemical Name	Tetrahydrofurfuryl bromide
Synonym	2-(Bromomethyl)tetrahydrofuran {LY} 2-(Bromomethyl)tetrahydrofuran {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrahydrofuran {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Bromomethyl)tetrah
MDL Number	MFCD00016894
CAS Number	1192-30-9
Reaxys-RN	102717
Beilstein Registry Number	17(5)1,80
PubChem Substance ID	14501
EC Number	214-750-3
Alfabeta Name	BROMOMETHYLTETRAHYDROFURAN 2()-
Chemical Name Translation	四氢呋喃甲基溴
Wiswesser Line Notation	T5OTJ B1E
InChIKey	VOHILFSOWRNVJJ-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00182489
InChI	InChI=1S/C5H9BrO/c6-4-5-2-1-3-7-5/h5H,1-4H2
Canonical SMILES	BrCC1CCCO1

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安全信息

RTECSLU6000000

Storage condition 2-8°C {LY} 2-8°C Refrigerator {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C

Signal word Warning

Hazard statements

H227 Combustible liquid 可燃液体
H302 Harmful if swallowed 吞食有害
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312
P301+P317
P302+P350
P302+P352
P302+P352+P332+P313+P362+P364
P304+P340
P305+P351+P338
P305+P351+P338+P337+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P403+P233
P403+P235
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R22 Harmful if swallowed 吞咽有害

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37 Wear suitable gloves 戴适当手套；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；

Hazard Codes Xn Xi

Warnings IRRITANT

UN Number 1993

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03416

WGK Germany3

其他信息

2-溴甲基四氢呋喃价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 T1808 四氢呋喃甲基溴 Tetrahydrofurfuryl Bromide 500G 2950元 2014/06/02 T1808 四氢呋喃甲基溴 Tetrahydrofurfuryl Bromide 25G 416元 2010/06/21 210940500 2-溴甲基四氢呋喃 Tetrahydrofurfuryl bromide 90%, tech. 50 GR 1646元
上游原料:四氢糠醇
用途一:医药中间体。
Acros Organics:(2-溴甲基)四氢呋喃 Tetrahydrofurfuryl bromide, tech., 90%(1192-30-9)
下游产品:alpha-(1-萘甲基)-2-四氢呋喃丙酸二乙胺基乙基酯草酸盐 --> 1-甲基-1H-吡唑-5-甲酸乙酯
TCI Shanghai:2-溴甲基四氢呋喃 Tetrahydrofurfuryl Bromide,>;95.0%(GC)(1192-30-9)
Alfa Aesar:溴化氢糠,95% Tetrahydrofurfuryl bromide, 95%(1192-30-9)
MOL 文件:1192-30-9.mol
图谱信息:2-溴甲基四氢呋喃(1192-30-9)质谱(MS) 2-溴甲基四氢呋喃(1192-30-9)红外图谱(IR1) 2-溴甲基四氢呋喃(1192-30-9)核磁图( 13 CNMR) 2-溴甲基四氢呋喃(1192-30-9)核磁图( 1 HNMR)
方法一:由四氢呋喃甲醇溴化而得。将苯和三溴化磷加入反应锅，搅拌冷却至0℃左右，均匀滴加四氢呋喃甲醇和吡啶的混合液，滴加完毕，搅拌1h，升温至20℃搅拌1h。放置过夜，减压蒸馏，收集55-130℃（2.67kPa）馏分，得四氢呋喃甲基溴。
MSDS 信息:2-(Bromomethyl)tetrahydrofuran(1192-30-9).msds