Antimony pentasulfide 五硫化二锑

CAS 1315-04-4 MFCD00016321

化学结构图

1315-04-4
SMILES: S=[Sb](=S)S[Sb](=S)=S

化学属性

Mol. FormulaS5Sb2
Mol. Weight403.85
Melting Point74-76 °C
Density4.12
TSCAYes
Solubility不溶于水、乙醇、硫酸铵溶液中,溶于浓盐酸,放出硫化氢气体,并游离出硫黄和生成三氯化锑,也溶于强碱及其硫化物溶液。隔绝空气加热于75℃时分解成三硫化二锑和硫。

别名和识别编码

Chemical NameAntimony pentasulfide
MDL NumberMFCD00016321
CAS Number1315-04-4
Synonym Antimony pentasulfide {LY} Antimony pentasulfide antimony pentasulfide {} {LY} Antimony pentasulfide {} {} {LY} Antimony pentasulfide {} {} {} {LY} Antimony pentasulfide {} {} {} {} {LY} Antimony pentasulfide {} {} {} {} {} {LY} Antimony pentasulfide {} {} {} {} {} {} {LY} Antimony pentasulfide {} {} {} {} {} {} {} {LY} Antimony pentasulfide {} {} {} {} {} {} {} {} {LY} Antimony pentasulfide {} {} {} {} {} {} {} {} {} {LY} Antimony pentasulfide {} {} {} {} {} {} {} {} {} {} {LY} Antimony pentasulfide {} {} {} {} {} {} {} {} {} {} {} {LY} Antimony pentasulfide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Antimony pentasulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Antimony pentasulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Antimony pentasulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Antimony pentasulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Antimony pentasulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {L
EC Number215-255-5
PubChem Substance ID16683083
Chemical Name Translation五硫化二锑
Merck Number13,703
Wiswesser Line NotationSB2 S3
InChIInChI=1S/5S.2Sb
Canonical SMILESS=[Sb][Sb]=S=S=S=S
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分类

  • {SNA} Antimony, Catalysis and Inorganic Chemistry, Chemical Synthesis

产品应用

  • 用于火柴、橡胶、颜料、医药等工业。

相关文献及参考

  • Merck: 14,697

安全信息

RTECSCC6125000
WGK Germany2
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Packing GroupIII
UN Number UN 3178 4.1/PG 2 UN3178
Risk Statements
  • R11 Highly flammable 非常易燃
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R51/53
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P304+P312
  • P304+P340
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P330 Rinse mouth. 漱口
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard statements
  • H228 Flammable solid 易燃固体
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
  • H332 Harmful if inhaled 吸入有害
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Hazard Codes F,Xn,N F
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Class4.1
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >10 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 54(4),68,1989

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EQSSDX Environmental Quality and Safety, Supplement.  (Stuttgart, Fed. Rep.
   Ger.)  V.1-5, 1975-76. Discontinued.  Volume(issue)/page/year: 1,1,1975

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : >166 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 8(7),25,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 458 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,23,1982

Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store

其他信息

  • 由硫代锑酸钠与硫酸作用而得。
  • Alfa Aesar:硫化锑,tech.Sbca66% Antimony(V) sulfide, tech. Sb ca 66%(1315-04-4)
  • 毒性分级:中毒
  • 灭火剂:水
  • 可燃性危险特性:明火, 高温, 氧化剂存在时即燃; 燃烧产生有毒硫氧化物和锑化物烟雾; 受潮分解有毒氮氧化物气体
  • 用途二:用于火柴、橡胶、颜料、医药等工业。
  • 爆炸物危险特性:震动或与强氧化剂自发反应爆炸
  • 五硫化二锑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 A18027 硫化锑, tech. Sb ca 66% Antimony(V) sulfide, tech. Sb ca 66% 50g 300元 2010/05/25 A18027 硫化锑, tech. Sb ca 66% Antimony(V) sulfide, tech. Sb ca 66% 250g 661元 2010/05/25 A18027 硫化锑, tech. Sb ca 66% Antimony(V) sulfide, tech. Sb ca 66% 10g 148元
  • 用途一:用于颜料的配制,也用作橡胶硫化剂
  • Sigma Aldrich:1315-04-4(sigmaaldrich)
  • 防护措施:三价锑化合物具有强的刺激作用。急性中毒表现对呼吸道和消化道及皮肤的刺激作用。最高容许浓度硫化锑(换算成Sb)规定为1mg/m3。工作人员要配戴防毒口罩等劳保防护用具。
  • 常规方法:用内衬聚乙烯塑料袋、外套聚丙烯编织袋包装。每袋净重20kg、50kg。 应贮存于通风、干燥库房,不可与氯酸钾等氧化剂共贮混运。
  • 职业标准:TWA 0.5 毫克 (锑)/立方米
  • MOL 文件:1315-04-4.mol
  • 储运特性:库房通风低温干燥; 与食品原料,氧化剂分开存放
  • 急性毒性:腹腔-大鼠 LD50: 1500 毫克/公斤; 腹腔-小鼠 LD50: 458 毫克/公斤
  • 不溶于水、乙醇、硫酸铵溶液中,溶于浓盐酸,放出硫化氢气体,并游离出硫黄和生成三氯化锑,也溶于强碱及其硫化物溶液。隔绝空气加热于75℃时分解成三硫化二锑和硫。
  • 外观性质:深橙黄色粉末。
  • MSDS 信息:五硫化锑(1315-04-4).msds
  • 类别:有毒物品

系列性分类


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