CAS 1344-43-0 MFCD00016226-Manganese Monoxide 一氧化锰 TAO{mole}

Manganese Monoxide 一氧化锰

CAS 1344-43-0 MFCD00016226

化学结构图

SMILES: O=[Mn]

化学属性

Mol. Formula	MnO
Mol. Weight	70.94
Density	5.45 g/mL at 25 °C(lit.)
TSCA	Yes
Melting Point	1650 °C
Solubility	不溶于水，溶于酸。

别名和识别编码

Chemical Name	Manganese Monoxide
Synonym	Manganese(ii)oxide {LY} Manganese(ii)oxide {} {LY} Manganese(ii)oxide {} {} {LY} Manganese(ii)oxide {} {} {} {LY} Manganese(ii)oxide {} {} {} {} {LY} Manganese(ii)oxide {} {} {} {} {} {LY} Manganese(ii)oxide {} {} {} {} {} {} {LY} Manganese(ii)oxide {} {} {} {} {} {} {} {LY} Manganese(ii)oxide {} {} {} {} {} {} {} {} {LY} Manganese(ii)oxide {} {} {} {} {} {} {} {} {} {LY} Manganese(ii)oxide {} {} {} {} {} {} {} {} {} {} {LY} Manganese(ii)oxide {} {} {} {} {} {} {} {} {} {} {} {LY} Manganese(ii)oxide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Manganese(ii)oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Manganese(ii)oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Manganese(ii)oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Manganese(ii)oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {}
MDL Number	MFCD00016226
CAS Number	1344-43-0
PubChem Substance ID	14940
EC Number	215-695-8
Chemical Name Translation	一氧化锰
Wiswesser Line Notation	.MN..O
LabNetwork Molecule ID	LN00194273
InChI	InChI=1S/Mn.O
Canonical SMILES	[Mn]=O

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安全信息

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Precautionary statements

P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338

RTECSOP0900000

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H335 May cause respiratory irritation 可能导致呼吸道刺激
H311 Toxic in contact with skin 皮肤接触中毒
H319 Causes serious eye irritation 严重刺激眼睛

WGK Germany3

Signal word Danger

GHS Symbol

Safety Statements

S36 Wear suitable protective clothing 穿戴适当的防护服；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R21 Harmful in contact with skin 与皮肤接触有害

Hazard Codes Xn

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ZVKOA6 Zhurnal Vsesoyuznogo Khimicheskogo Obshchestva im. D.I. Mendeleeva.
   Journal of the D.I. Mendeleeva All-Union Chemical Society.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.5-    1960-
   Volume(issue)/page/year: 19,186,1974

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intratracheal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 20(1),25,1955

Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store

其他信息

下游产品:二氧化锰 --> 碳酸锰 --> 硫酸锰 --> 锰 --> 四水硝酸锰(II) --> 氯化锰 --> 异丁酸异戊酯
用途二:用作生产铁氧体的原料、涂料和清漆的干燥剂、戊醇制造的催化剂、饲料辅助剂、微量元素肥料等。也用于医药、冶炼、焊接、织物还原印染、玻璃着色、油脂漂白、陶瓷窑业及干电池的制造等。
方法一:还原法将软锰矿与煤粉按质量比值1：0.2进行混合，在800℃下进行还原焙烧4h，生成一氧化锰。反应产物在隔绝空气条件下进行冷却，然后过筛，制得一氧化锰成品。其 MnO2+C→MnO+CO MnO2+CO→MnO+CO2
毒性:吸入氧化锰粉尘，可引起入的锰尘肺。其他参见金属锰。最高容许浓度：在无定形二氧化硅的凝聚气溶胶中含有氧化锰1 mg／m 3 。
Alfa Aesar:氧化锰(II),Mn76.0-78.0%,typically99% Manganese(II) oxide, Mn 76.0-78.0%, typically 99%(1344-43-0)
MSDS 信息:一氧化锰(1344-43-0).msds
3400℃时解离升华。不溶于水，溶于酸和氯化铵。在热浓氯化铵溶液中，形成氯化锰及氨。
灭火剂:水, 二氧化碳, 干粉, 砂土
一氧化锰价格(试剂级):更新日期产品编号产品名称包装价格 2010/05/25 11870 氧化锰(II), Mn 76.0-78.0%, typically 99% Manganese(II) oxide, Mn 76.0-78.0%, typically 99% 500g 354元 2010/05/25 11870 氧化锰(II), Mn 76.0-78.0%, typically 99% Manganese(II) oxide, Mn 76.0-78.0%, typically 99% 2kg 1040元 2010/05/25 44441 氧化锰(II), 99.99% (metals basis) Manganese(II) oxide, 99.99% (metals basis) 50g 4074元
毒性分级:中毒
参考质量标准:参考标准指标名称指标一氧化锰(MnO)/%≥ 80 锰(Mn)/%≥ 62 二氧化锰(MnO2)/%≤ 2 氧化铁(Fe2O3)/%≤ 3.8 氧化铝(A12O3)/%≤ 3.0 氧化钙(CaO)/%≤ 0.3 氧化镁(MgO)/%≤ 0.2 二氧化硅(SiO2)/%≤ 4 铅(Pb)/%≤ 0.1 铜(Cu)/%≤ 0.01 锌(Zn)/%≤ 0.055 砷(As)/%≤ 0.01 细度(80目筛余)/%≤ 10
类别:有毒物质
上游原料:二氧化锰
MOL 文件:1344-43-0.mol
用途一:用作饲料添加剂、微量元素肥料、铁氧体原料、涂料和清漆干燥剂等
储运特性:库房低温, 通风, 干燥
可燃性危险特性:不燃, 火场排出含锰辛辣刺激烟雾
图谱信息:一氧化锰(1344-43-0)红外图谱(IR1)
外观性质:灰绿色粉末。
职业标准:TWA 5 毫克(锰)/立方米
Sigma Aldrich:1344-43-0(sigmaaldrich)
急性毒性:皮下-小鼠 LD50: 1000 毫克/公斤