N,N-Dimethylformamide di-Tert-Butyl Acetal N,N-二甲基甲酰胺缩二叔丁基醇
CAS 36805-97-7 MFCD00015002
化学结构图
SMILES: CN(C)C(OC(C)(C)C)OC(C)(C)C
化学属性
| Mol. Formula | (CH3)2NCH[OC(CH3)3]2 |
|---|---|
| Mol. Weight | 203 |
| Refractive index | 1.4120 to 1.4150 |
| Boiling Point | 56-57 |
| Density | 0.848 |
| Flash Point | 33°C(lit.) |
| TSCA | No |
别名和识别编码
| Chemical Name | N,N-Dimethylformamide di-Tert-Butyl Acetal |
|---|---|
| Synonym | N,N-DIMETHYLFORMAMIDE DI-T-BUTYL ACETAL N,N-Dimethyl-1,1-bis[(2-methylpropan-2-yl)oxy]methanamine DMF-二特丁基基缩醛 N,N-Dimethylformamide di-tert-butyl acetal, tech. 90% |
| CAS Number | 36805-97-7 |
| PubChem Substance ID | 87567826 |
| EC Number | 253-222-7 |
| Beilstein Registry Number | 969629 |
| MDL Number | MFCD00015002 |
| Reaxys-RN | 969629 |
| Chemical Name Translation | N,N-二甲基甲酰胺缩二叔丁基醇 |
| InChIKey | DBNQIOANXZVWIP-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN01739685 |
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分类
- {SNA} Acetals/Ketals/Ortho Esters, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Building Blocks, Chemical Synthesis, D, DID - DIN, Orga
- {SNA} Acetals/Ketals/Ortho Esters, Alkylation Reagents, Amides, Amines, Building Blocks, Chemical Synthesis, DMF-Dialkylacetals, Derivatization Reagents, Derivatization Reagents GC, GC Derivatization Reagents, by Application, Organic Building Blocks, Oxygen Compounds, Reagents for Alkylation & Esterification, Steroids, 分析/色谱, 分析试剂
- {SNA} Acetals/Ketals/Ortho
相关文献及参考
- The conversion of carboxylic acids to their esters using DMF acetals (see for example, N,N-Dimethylformamide dimethyl acetal, A15350) can be extended to the preparation of t-butyl esters by using excess reagent in benzene or toluene as solvent: Synthesis, 135 (1983).
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P370+P378
- P305+P351+P338+P337+P313
- R10 Flammable 易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
其他信息
- Sigma Aldrich:36805-97-7(sigmaaldrich)
- MOL 文件:36805-97-7.mol
- 敏感性:Moisture Sensitive
- MSDS 信息:1,1-Di-tert-butoxy-N,N-dimethylmethylamine(36805-97-7).msds
- N,N-二甲基甲酰胺二叔丁基缩醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D1303 N,N-二甲基甲酰胺-二叔丁缩醛[用于酯化] N,N-Dimethylformamide Di-tert-butyl Acetal [for Esterification] 5ML 1430元 2014/06/02 D1303 N,N-二甲基甲酰胺-二叔丁缩醛[用于酯化] N,N-Dimethylformamide Di-tert-butyl Acetal [for Esterification] 25ML 4910元 2010/05/25 L00431 N,N-二甲基甲酰胺二叔丁基乙缩醛, tech. 90% N,N-Dimethylformamide di-tert-butyl acetal, tech. 90% 5g 749元
- F:10-21
- N,N-二甲基甲酰胺二叔丁基缩醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D1303 N,N-二甲基甲酰胺-二叔丁缩醛[用于酯化] N,N-Dimethylformamide Di-tert-butyl Acetal [for Esterification] 5ML 1180元 2011/04/16 D1303 N,N-二甲基甲酰胺-二叔丁缩醛[用于酯化] N,N-Dimethylformamide Di-tert-butyl Acetal [for Esterification] 25ML 4050元 2010/05/25 L00431 N,N-二甲基甲酰胺二叔丁基乙缩醛, tech. 90% N,N-Dimethylformamide di-tert-butyl acetal, tech. 90% 5g 749元
- Alfa Aesar:N,N-二甲基甲酰胺二叔丁基乙缩醛,tech.90% N,N-Dimethylformamide di-tert-butyl acetal, tech. 90%(36805-97-7)
- TCI Shanghai:N,N-二甲基甲酰胺-二叔丁缩醛[用于酯化] N,N-Dimethylformamide Di-tert-butyl Acetal [for Esterification],>;98.0%(N)(36805-97-7)
